Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil

QSpace/Manakin Repository

Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil

Show simple item record


dc.contributor.author AlQaradawi, S. Y.
dc.contributor.author Bazzi, Hassan S.
dc.contributor.author Mostafa, A.
dc.contributor.author Nour, E.M.
dc.date.accessioned 2009-12-28T07:34:25Z
dc.date.available 2009-12-28T07:34:25Z
dc.date.issued 2008-06-10
dc.identifier.citation Volume 71, Issue 4, 15 December 2008, Pages 1594-1598 en_US
dc.identifier.uri http://dx.doi.org/10.1016/j.saa.2008.06.010
dc.identifier.uri http://hdl.handle.net/10576/10513
dc.description.abstract The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental analysis. The results show that the formed solid CT-complexes have the formulas [(TMTACN)I]I3, [(TMTACN)(TCNE)5] and [(TMTACN)(TCNQ)3] in full agreement with the known reaction stoichiometries in solution. The chloranil CT-solid complex cannot be isolated in pure form. en_US
dc.language.iso en en_US
dc.subject 1,4,7-Trimethyl-1,4,7-triazacyclononane en_US
dc.subject Infrared en_US
dc.subject Iodine en_US
dc.subject Solid CT-complexes en_US
dc.subject Structure en_US
dc.subject TCNE en_US
dc.subject TCNQ en_US
dc.subject Thermal en_US
dc.title Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil en_US
dc.type Article en_US

Files in this item

Files Size Format View
Synthesis, spec ... E, TCNQ and chloranil .pdf 330.6Kb PDF View/Open

This item appears in the following Collection(s)

Show simple item record

Search QSpace


Advanced Search

Browse

My Account