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Author AlQaradawi, Siham Y.en_US
Author Bazzi, Hassan S.en_US
Author Mostafa, Adelen_US
Author Nour, El-Metwallyen_US
Available date 2009-12-28T07:34:25Zen_US
Publication Date 2008-06-10en_US
Publication Name Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Citation AlQaradawi, S. Y., Bazzi, H. S., Mostafa, A., & Nour, E.-M. (2008). Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71(4), 1594–1598en_US
ISSN 1386-1425en_US
URI http://dx.doi.org/10.1016/j.saa.2008.06.010en_US
URI http://hdl.handle.net/10576/10513en_US
Abstract The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental analysis. The results show that the formed solid CT-complexes have the formulas [(TMTACN)I]I3, [(TMTACN)(TCNE)5] and [(TMTACN)(TCNQ)3] in full agreement with the known reaction stoichiometries in solution. The chloranil CT-solid complex cannot be isolated in pure form.en_US
Language enen_US
Publisher Elsevieren_US
Subject 1,4,7-Trimethyl-1,4,7-triazacyclononaneen_US
Subject Infrareden_US
Subject Iodineen_US
Subject Solid CT-complexesen_US
Subject Structureen_US
Subject TCNEen_US
Subject TCNQen_US
Subject Thermalen_US
Title Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranilen_US
Type Articleen_US


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