| dc.contributor.author |
AlQaradawi, S. Y. |
|
| dc.contributor.author |
Bazzi, Hassan S. |
|
| dc.contributor.author |
Mostafa, A. |
|
| dc.contributor.author |
Nour, E.M. |
|
| dc.date.accessioned |
2009-12-28T07:34:25Z |
|
| dc.date.available |
2009-12-28T07:34:25Z |
|
| dc.date.issued |
2008-06-10 |
|
| dc.identifier.citation |
Volume 71, Issue 4, 15 December 2008, Pages 1594-1598 |
en_US |
| dc.identifier.uri |
http://dx.doi.org/10.1016/j.saa.2008.06.010 |
|
| dc.identifier.uri |
http://hdl.handle.net/10576/10513 |
|
| dc.description.abstract |
The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental analysis. The results show that the formed solid CT-complexes have the formulas [(TMTACN)I]I3, [(TMTACN)(TCNE)5] and [(TMTACN)(TCNQ)3] in full agreement with the known reaction stoichiometries in solution. The chloranil CT-solid complex cannot be isolated in pure form. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.subject |
1,4,7-Trimethyl-1,4,7-triazacyclononane |
en_US |
| dc.subject |
Infrared |
en_US |
| dc.subject |
Iodine |
en_US |
| dc.subject |
Solid CT-complexes |
en_US |
| dc.subject |
Structure |
en_US |
| dc.subject |
TCNE |
en_US |
| dc.subject |
TCNQ |
en_US |
| dc.subject |
Thermal |
en_US |
| dc.title |
Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil |
en_US |
| dc.type |
Article |
en_US |