Preparation, spectroscopic and structural studies on charge-transfer complexes of 2,9-dimethyl-1,10-phenanthroline with some electron acceptors

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Preparation, spectroscopic and structural studies on charge-transfer complexes of 2,9-dimethyl-1,10-phenanthroline with some electron acceptors

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dc.contributor.author Gaballa, A.S.
dc.contributor.author Wagner, C.
dc.contributor.author Teleb, S. M.
dc.contributor.author Nour, E-M.
dc.contributor.author Elmosallamy, M.A.F.
dc.contributor.author Kaluđerović, G.N.
dc.contributor.author Schmidt, H.
dc.contributor.author Steinborn, D.
dc.date.accessioned 2010-01-07T07:15:50Z
dc.date.available 2010-01-07T07:15:50Z
dc.date.issued 2007-07-02
dc.identifier.citation Volume 876, Issue 1-3, 30 March 2008, Pages 301-307 en_US
dc.identifier.uri http://dx.doi.org/10.1016/j.molstruc.2007.07.003
dc.identifier.uri http://hdl.handle.net/10576/10617
dc.description.abstract Charge-transfer (CT) complexes formed in the reactions of 2,9-dimethyl-1,10-phenanthroline (Me2phen) with some acceptors such as chloranil (Chl), picric acid (HPA) and chloranilic acid (H2CA) have been studied in the defined solvent at room temperature. Based on elemental analysis and infrared spectra of the solid CT-complexes along with the photometric titration curves for the reactions, obtained data indicate the formation of 1:1 charge-transfer complexes [(Me2phen)(Chl)] (1), [(Me2phenH)(PA)] (2) and [(Me2phenH)(HCA)] (3), respectively, was proposed. In the three complexes, infrared and 1H NMR spectroscopic data indicate a charge-transfer interaction and as far as complexes 2 and 3 are concerned this interaction is associated with a hydrogen bonding. The formation constants for the complexes (KC) were shown to be dependent upon the nature of the electron acceptors used. The X-ray structure of complex 3 indicate the formation of dimeric units [Me2phenH]2[(HCA)2] in which the two anions (HCA)− are connected by two O–HO hydrogen bonds whereas the cations and anions are joined together by strong three-center (bifurcated) N–HO hydrogen bonds. Furthermore, the cations are arranged in a π–π stacking. en_US
dc.language.iso en en_US
dc.subject Charge transfer en_US
dc.subject 2,9-Dimethyl-1,10-phenanthroline en_US
dc.subject Electron acceptors en_US
dc.subject UV–visible en_US
dc.subject IR en_US
dc.subject 1H NMR en_US
dc.subject X-ray structure analysis en_US
dc.title Preparation, spectroscopic and structural studies on charge-transfer complexes of 2,9-dimethyl-1,10-phenanthroline with some electron acceptors en_US
dc.type Article en_US

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