| Author | Wang, Y. |
| Author | Hao, W. |
| Author | Jacquemin, J. |
| Author | Goodrich, P. |
| Author | Atilhan, M. |
| Author | Khraisheh, Majeda |
| Author | Rooney, D. |
| Author | Thompson, J. |
| Available date | 2022-05-21T08:36:54Z |
| Publication Date | 2015 |
| Publication Name | Journal of Chemical and Engineering Data |
| Resource | Scopus |
| Identifier | http://dx.doi.org/10.1021/je5004669 |
| URI | http://hdl.handle.net/10576/31218 |
| Abstract | This paper describes the extraction of C5-C8 linear α-olefins from olefin/paraffin mixtures of the same carbon number using silver(I)/N,N-dimethylbenzamide bis(trifluoromethylsulfonyl)imide ([Ag(DMBA)2][Tf2N]) or silver(I)/propylamine bis(trifluoromethylsulfonyl)imide ([Ag(PrNH2)2][Tf2N]) as the extracting agent. The separation performance of the system increased with increasing chain length. [Ag(DMBA)2][Tf2N] appeared to outperform [Ag(PrNH2)2][Tf2N] in terms of both selectivity and distribution coefficient. The [Ag(DMBA)2][Tf2N] system was successfully modeled using the universal quasi-chemical activity coefficient (UNIQUAC) model. These results support the potential future development of amine/amide-based ligands for producing soluble silver complexes useful for the separation of olefins from paraffins. |
| Language | en |
| Publisher | American Chemical Society |
| Title | Enhancing liquid-phase olefin-paraffin separations using novel silver-based ionic liquids |
| Type | Article |
| Pagination | 28-36 |
| Issue Number | 1 |
| Volume Number | 60 |
