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AuthorCarchini, Giuliano
AuthorHamza, Ahmed
AuthorHussein, Ibnelwaleed A.
AuthorSaad, Mohammed
AuthorMahmoud, Mohamed
AuthorShawabkeh, Reyad
AuthorAparicio, Santiago
Available date2024-03-18T06:24:35Z
Publication Date2023
Publication NameInternational Journal of Hydrogen Energy
ResourceScopus
ISSN3603199
URIhttp://dx.doi.org/10.1016/j.ijhydene.2022.11.174
URIhttp://hdl.handle.net/10576/53136
AbstractHydrogen is one of the clean energy sources that can be used instead of fossil fuel sources to reduce greenhouse emissions. However, hydrogen supply intermittency significantly reduces the deployment and reliability of this energy resource. Therefore, this work investigates the underground storage of hydrogen in depleted gas reservoirs to avoid seasonal fluctuations in hydrogen supply and assure long-term energy security. The obtained results from molecular simulation (Density Functional Theory) revealed hydrogen is adsorbed physically on calcite (104) and silica (001) surfaces on different adsorption configurations. This conclusion is supported by low adsorption energies (−0.14 eV for calcite and −0.09 for silica) and by Bader charge analysis, which showed no indication of charge transfer. The experimental results illustrated that hydrogen has a very low adsorption affinity toward carbonate and sandstone rocks in the temperature range of 50–100 °C and pressure up to 20 bar. These results show the potential of depleted gas reservoirs to store hydrogen for s is useful in hydrogen recovery as no hydrogen will be adsorbed to the rock surface of conventional gas reservoirs.
SponsorThe authors would like to acknowledge the Qatar National Research Fund (a member of Qatar Foundation) for funding through Grant # NPRP13S-1231-190009. Al-Salam Petroleum Services Company, Qatar, is also acknowledged for co-funding this project. The findings achieved herein are solely the responsibility of the authors. The authors would also like to acknowledge Qatar University for providing support.
Languageen
PublisherElsevier
SubjectCalcite
Density functional theory
Depleted gas reservoirs
Hydrogen adsorption
Hydrogen storage
Molecular simulation
TitleHydrogen storage in gas reservoirs: A molecular modeling and experimental investigation
TypeArticle
Pagination7419-7430
Issue Number20
Volume Number48
dc.accessType Abstract Only


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