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AuthorBarakat, Nasser A.M.
AuthorAhmed, Enas
AuthorAbdelkareem, Mohammad Ali
AuthorFarrag, T. E.
AuthorAl-Meer, Saeed
AuthorAl-Deyab, Salem
AuthorElsaid, Khaled
AuthorNassar, M. M.
Available date2019-11-11T11:22:45Z
Publication Date2015-01-01
Publication NameInternational Journal of Hydrogen Energyen_US
Identifierhttp://dx.doi.org/10.1016/j.ijhydene.2015.06.049
CitationBarakat, Nasser A.M. et. al. "Ammonium phosphate as promised hydrogen storage material" , International Journal of Hydrogen Energy, Volume 40 (2015) P.p. 10103-10110
ISSN0360-3199
URIhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84937512675&origin=inward
URIhttp://hdl.handle.net/10576/12311
AbstractHydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. Most of the reported hydrogen storage materials are either expensive or based on synthetically complicated compounds. Ammonium phosphates are cheap and available product; it is being used as fertilizer. These compounds could be utilized as hydrogen storage materials. Stoichiometrically, mono-, di- and tri-ammonium phosphate can lead to evolve 3.875, 7.867 and 11.903 hydrogen equivalent, respectively. Using Pt/C (20 wt %) leads to produce 17.28, 11.35 and 10.15% from the equivalent hydrogen in the mono-, di- and tri-ammonium phosphate, respectively. Analyzing the obtained gases by GC confirms evolution of pure hydrogen. Moreover, ion chromatography detects and ions in the liquid which indicates hydrolysis of the ammonium phosphate. Ni/C and Co/C NPs can be exploited as catalysts; Ni/C containing 20 wt% metal reveals comparable results to Pt/C. Overall, this study opens promising avenue to develop new catalysts to enhance the hydrolysis of ammonium phosphate to produce hydrogen. Comparing to the reported hydrogen storage materials, ammonium phosphates possess comparable hydrogen content 97.28, 118.3 and 115.72 kg/m<sup>3</sup> for mono-, di- and tri-ammonium phosphate, respectively which is very close to the MgH<inf>2</inf> (115.5 kg/m<sup>3</sup>) and not so far from ammonia borane (148.2 kg/m<sup>3</sup>). However, in contrast to these compounds, hydrogen can be released from the introduced storage materials by hydrolysis only using the proper catalyst. Furthermore, the hydrolysis process results in producing different acids; nitrous, nitric and phosphoric acid which should be considered in the reactor construction precautions.
Languageen
PublisherElsevier
SubjectAmmonium phosphate
SubjectCo/C nanoparticles
SubjectHydrogen storage materials
SubjectNi/C nanoparticles
TitleAmmonium phosphate as promised hydrogen storage material
TypeArticle
Pagination10103-10110
Issue Number32
Volume Number40
elsevier.identifier.scopusid SCOPUS_ID:84937512675


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