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AuthorTeng Z.
AuthorLi W.
AuthorTang Y.
AuthorElzatahry A.
AuthorLu G.
AuthorZhao D.
Available date2020-04-23T14:21:35Z
Publication Date2019
Publication NameAdvanced Materials
ResourceScopus
ISSN9359648
URIhttp://dx.doi.org/10.1002/adma.201707612
URIhttp://hdl.handle.net/10576/14384
AbstractHollow periodic mesoporous organosilicas (PMOs) with molecularly homogeneous organic functional groups in the inorganic pore walls are attracting more and more attention due to the high surface areas, tunable pore sizes, low densities, large cavities in the center, permeable thin shells, and versatile organic–inorganic hybrid frameworks, which make them promising in a variety of applications including adsorption, catalysis, drug delivery, and nanotheranostics. Herein, recent advances in the synthesis of hollow PMO nanoparticles with various organic moieties are summarized, and the mechanism and new insights of synthesis approaches, including hard‐core templating methods, liquid‐interface assembly methods, and the interfacial reassembly and transformation strategy are discussed in‐depth. Meanwhile, the design principles, properties, and synthetic strategies for some smart hollow architectures such as multishelled hollow PMOs, yolk–shell structured PMOs, and nonspherical hollow PMOs are discussed. Moreover, the typical applications of hollow PMO nanomaterials as nanoreactors for chemical transformations and nanoplatforms for biomedicine are summarized. Finally, the challenges and prospects for the future development of hollow PMOs are described.
SponsorThis work was supported by the State Key Basic Research Program of the PRC (Grant Nos. 2014CB744504, 2014CB744501, 2013CB934104, and 2017YFA0207300), the NSFC of China (Grant nos. 21733003, U1463206, and 81530054), the Key Basic Research Program of Science and Technology Commission of Shanghai Municipality (Grant No. 17JC1400100), and the Natural Science Foundation of Jiangsu Province (Grant No. BK20160017). W.L., A.E., and D.Y.Z. extend their appreciation to the International Scientific Partnership Program ISPP at King Saud University for funding this research work through ISPP# 0018.
Languageen
PublisherWiley-VCH Verlag
Subjectapplications
hollow
mesoporous
organosilica
synthesis
TitleMesoporous Organosilica Hollow Nanoparticles: Synthesis and Applications
TypeArticle
Issue Number38
Volume Number31
dc.accessType Abstract Only


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