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Roll-over cyclometalation: A versatile tool to enhance the catalytic activity of transition metal complexes
( Elsevier B.V. , 2018 , Article)
Roll-over cyclometalation is a special case of cyclometalation. While in classical cyclometalation, C,H-activation (deprotonation or oxidative addition) has to occur at the ligand to result in a metallacycle, in roll-over ...