Application of magnetic nanoparticles for the removal of oil from oil-in-water emulsion: Regeneration/reuse of spent particles
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Date
2021Metadata
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The recovery of oil from produced water (PW) is integral for minimizing energy resource loses and creating an appropriate treatment method for a sustainable environment. In this study, Fe3O4 magnetic nanoparticles (Fe-MNP) were synthesized using the combustion synthesis method (CSM) in the temperature range of 150 to 350 °C. The Fe-MNP were characterized using various analytical techniques and were used to recover oil from oil-in-water emulsion (O-in-W-emu) at various concentrations. The effects of the process parameters including, pH, oil concentration (Coil), Fe-MNP dose (DMNP), the surfactant concentration (Csur) on the demulsification efficiency (%ηdem), and the percentage oil removal (%Roil) were studied. Further, the re-usability of the as-synthetized Fe-MNP were examined and reported. The as-synthetized Fe-MNP achieved a %ηdem ≥ 98% for Coil in the range of 200–660 mg/L. Up to 98.6% of the %Roil was attained for Coil in the range from 0 to 800 mg/L using only a DMNP of 10 mg/L. A lower DMNP of 5 mg/L recovered up to 55.6% of the oil, while increasing the DMNP > 50 mg/L did not significantly affect the %ηdem nor the %Roil. The observed %Roil at a pH of 4 and Csur of 0.05 g/L was observed to be > 90 ± 0.1% and decreased by either rising the pH to 7 or increasing the Csur to 0.1 g/L. This change is due to the decrease in the emulsion stability and the formation of fine oil droplets. Stability and re-usability tests of the as-synthetized Fe-MNP exhibited an effective oil recovery of up to 90% after 7 cycles. The as-synthesized Fe-MNP demulsifier exhibited an excellent adsorption capacity of 51 mg/g and best fit the Langmuir and Freundlich models. The kinetics of the oil recovery process are properly adapted to fit the pseudo-second-order model for the Coil and DMNP. The tests indicated that the fastest and highest adsorption capacity was achieved at a DMNP (100 mg/L). As such, the results indicate that the developed Fe-MNP are an effective and reusable demulsifier, which are suitable for the oil recovery of produced water (PW).
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