Impact of ionic liquids on silver thermoplastic polyurethane composite membranes for propane/propylene separation
| Author | Wang, Y. |
| Author | Goh, T. Y. |
| Author | Goodrich, P. |
| Author | Atilhan, M. |
| Author | Khraisheh, Majeda |
| Author | Rooney, D. |
| Author | Thompson, J. |
| Author | Jacquemin, J. |
| Available date | 2022-05-21T08:36:53Z |
| Publication Date | 2020 |
| Publication Name | Arabian Journal of Chemistry |
| Resource | Scopus |
| Identifier | http://dx.doi.org/10.1016/j.arabjc.2017.05.008 |
| Abstract | This work describes newly synthesized composite polymeric membranes and their utilization in propane/propylene separation in a gas mixture. The nonporous composite polymers were successfully synthesized by using thermoplastic polyurethane (TPU) and several silver salts/silver salts with ionic liquids (ILs). Our studies showed that silver bis(trifluoromethanesulfonyl)imide (Ag[Tf2N]) containing membranes outperformed other silver salt containing membranes in terms of selectivity. In addition, to this finding, ILs, as additives for the membranes, enhanced the selectivity by facilitating improved coordination of the olefin with the silver ions in the dense composite polymers. |
| Language | en |
| Publisher | Elsevier B.V. |
| Subject | Composite polymer Ionic liquids Membrane separation Propane/propylene separation |
| Type | Article |
| Pagination | 404-415 |
| Issue Number | 1 |
| Volume Number | 13 |
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Chemical Engineering [1174 items ]