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Ethanol dehydrogenation mechanism on cuni catalysts for hydrogen production
(
TechConnect
, 2016 , Conference Paper)
Ethanol dehydrogenation mechanism was investigated over catalysts containing Cu and Ni metals prepared by solution combustion synthesis. In situ DRIFTS studies were conducted on individual metals (Cu and Ni) as well as on ...
CO2 Capture Using Aqueous Potassium Carbonate Promoted by Ethylaminoethanol: A Kinetic Study
(
American Chemical Society
, 2016 , Article)
Kinetics of absorption of CO2 in an aqueous potassium carbonate (K2CO3) promoted by ethylaminoethanol (EAE) solution (hereafter termed as APCE solvent) was investigated in a glass stirred cell reactor by employing a fall ...
Solar hydrogen production via erbium oxide based thermochemical water splitting cycle
(
American Institute of Physics Inc.
, 2016 , Article)
The erbium oxide based water splitting (Eb-WS) cycle was thermodynamically studied by using the HSC Chemistry software and databases. The first step of the Eb-WS cycle involves thermal reduction of Er2 O3, whereas the ...
Solar hydrogen production via a samarium oxide-based thermochemical water splitting cycle
(
MDPI AG
, 2016 , Article)
The computational thermodynamic analysis of a samarium oxide-based two-step solar thermochemical water splitting cycle is reported. The analysis is performed using HSC chemistry software and databases. The first (solar-based) ...
Effectiveness of Ni incorporation in iron oxide crystal structure towards thermochemical CO2 splitting reaction
(
Elsevier Ltd
, 2017 , Article)
In this study, Ni-doped iron oxide (NixFe3−xO4) materials were synthesized via the 1,2-epoxypropane assisted sol-gel method by varying the molar concentration of Ni from x=0.2 to 1. Sol-gel derived NixFe3−xO4 gels were ...
Study of ethanol dehydrogenation reaction mechanism for hydrogen production on combustion synthesized cobalt catalyst
(
Elsevier Ltd
, 2017 , Article)
Cobalt nanoparticles synthesized via solution combustion synthesis were used to study the decomposition mechanism of ethanol for hydrogen production. Thermodynamic studies were conducted on the synthesis of cobalt nanoparticles ...
Assessment of CexZryHfzO2 based oxides as potential solar thermochemical CO2 splitting materials
(
Elsevier Ltd
, 2016 , Article)
In this paper, we report the synthesis, characterization, and assessment of CexZryHfzO2 (CZH) materials for solar thermochemical splitting of CO2 in up to 20 consecutive thermochemical cycles. CZH materials with different ...
Sol-gel derived CeO2-Fe2O3 nanoparticles: Synthesis, characterization and solar thermochemical application
(
Elsevier Ltd
, 2016 , Article)
Synthesis of CeO2-Fe2O3 nanoparticles via propylene oxide (PO) aided sol-gel method for the production of solar fuels via thermochemical H2O/CO2 splitting cycles is reported in this paper. For the synthesis of CeO2-Fe2O3, ...
Solar co-production of samarium and syngas via methanothermal reduction of samarium sesquioxide
(
Elsevier Ltd
, 2016 , Article)
This paper reports the thermodynamic analysis of the solar methanothermal reduction of Sm2O3 for the co-production of Sm and syngas in (a) Sm-Syngas open cycle, and (b) Sm-Syngas closed cycle. As per the chemical thermodynamic ...
A comparative thermodynamic analysis of samarium and erbium oxide based solar thermochemical water splitting cycles
(
Elsevier Ltd
, 2017 , Article)
This paper reports a thermodynamic comparison between the samarium and erbium oxide based solar thermochemical water splitting cycles. These cycles are a two-step process in which the metal oxide is first thermally reduced ...