Browsing Chemistry & Earth Sciences by Title
Now showing items 334-353 of 560
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Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions
( American Chemical Society (ACS) , 2015 , Article)Two new pentadentate {N5} donor ligands based on the N4Py (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) framework have been synthesized, viz. [N-(1-methyl-2-benzimidazolyl)methyl-N-(2-pyridyl)methyl-N-(bi ... -
A novel approach of encapsulating curcumin and succinylated derivative in mannosylated-chitosan nanoparticles
( Elsevier , 2022 , Article)Curcumin (CUR) manifests anti-colon cancer activity but suffers from low solubility, bioavailability, and instability, rendering it not as effective as its chemotherapeutic cousins. Here, we conjugate CUR to succinic ... -
Novel biomedical sensors for flow injection potentiometric determination of creatinine in human serum
( Wiley-VCH Verlag , 2005 , Article)Coated-wire (CW) and tubular (Tu) type membrane sensors for creatinine are developed. These consist of creatinine tungstophosphate(CTP), creatinine molybdophosphate (CMP) and creatinine picrolonate (CPC) ion-pair complexes ... -
Novel charge transfer complexes of the donor 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane and the acceptors iodine, TCNE, and TCNQ
( Elsevier , 2011 , Article)Abstract Novel charge transfer complexes have been formed in the reaction of the interesting powerful electron donor 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane (HMHACOD) with σ-electron acceptor iodine ... -
Novel Cu (II) and Zn (II) complexes of 8-hydroxyquinoline derivatives as effective corrosion inhibitors for mild steel in 1.0?M HCl solution: Computer modeling supported experimental studies
( Elsevier B.V. , 2019 , Article)In this work, we have synthesized and characterized novel complexes of copper (II) and zinc (II). These complexes were obtained by reacting of 5-azidomethyl-8-hydroxyquinoline with copper chloride dihydrate and zinc chloride ... -
A Novel Cyclopentadienone and its Ruthenium and Iron Tricarbonyl Complexes
( Wiley , 2021 , Article)A simple and efficient protocol allows the oxidation of the cyclopentadiene derivative 5H-dibenzo[e,h]-dibenzo[3,4 : 6,7]cyclohept[1,2-a]azulene (CpCH) provide according ketone CpCO. Comparable to the situation found for ... -
A Novel Green Synthesis of Thalidomide and Analogs
( Hindawi Limited , 2017 , Article)Thalidomide and its derivatives are currently under investigation for their antiangiogenic, immunomodulative, and anticancer properties. Current methods used to synthesize these compounds involve multiple steps and extensive ... -
Novel Ni-B/AlN nanocomposite coatings for oil and gas industry
( National Assoc. of Corrosion Engineers International , 2018 , Conference Paper)Corrosion is a major cause of materials and equipment failure in the oil and gas industry, and its prevention is crucial to ensure reliability of the assets. Towards, this goal, Ni-B/AlN nanocomposite coatings were synthesized ... -
Novel palladium(II) and platinum(II) complexes with a fluoropiperazinyl based ligand exhibiting high cytotoxicity and anticancer activity in vitro
( Hindawi Publishing Corporation , 2016 , Article)cis-Dichloro-palladium(II) and cis-dichloro-platinum(II) complexes (2, 4) of the general formula [M(N-N)Cl2] (M=Pd(II) and Pt(II), N-N= 1,2-diamino-4-fluoro-5-(4-methyl-1-piperazinyl) benzene, (DFMPB)) and the dicationic ... -
A novel platinum complex of the histone deacetylase inhibitor belinostat: Rational design, development and in vitro cytotoxicity
( Elsevier Inc. , 2013 , Article)The successful design and synthesis of a novel Pt complex of the histone deacteylase inhibitor belinostat are reported. Molecular modelling assisted in the identification of a suitable malonate derivative of belinostat(mal-p-Bel) ... -
Novel Polyepoxysuccinic Acid-Grafted Polyacrylamide as a Green Corrosion Inhibitor for Carbon Steel in Acidic Solution.
( American Chemical Society , 2023 , Article)Utilizing green corrosion inhibitors has been classified among the most efficient and economical mitigation practices against metallic degradation and failure. This study aims to integrate the features of green and ... -
Novel potentiometric copper (II) selective membrane sensors based on cyclic tetrapeptide derivatives as neutral ionophores
( Elsevier , 2005 , Article)Two novel membrane sensors sensitive and reasonably selective for Cu2+ ions are described. These are based on the use of newly synthesized cyclic tetrapeptide derivatives as neutral ionophores and sodium tetraphenylborate ... -
Novel thorium membrane sensors with anionic response based on trioctylphosphine oxide and toluate ionophores
( Wiley-VCH Verlag , 2008 , Article)Two novel potentiometric polymeric membrane sensors for rapid and accurate determination of thorium are described. These are based on the use of trioctylphosphine oxide (TOPO) and thorium toluate (Th-TA) as ionophores ... -
On Chip Optical Modulator using Epsilon-Near-Zero Hybrid Plasmonic Platform
( Nature Publishing Group , 2019 , Article)In this work, we propose a micro-scale modulator architecture with compact size, low insertion loss, high extinction ratio, and low energy/bit while being compatible with the silicon-on-insulator (SOI) platform. This is ... -
On the encapsulation of Olsalazine by ?-cyclodextrin: A DFT-based computational and spectroscopic investigations
( Elsevier B.V. , 2019 , Article)In this work, the supramolecular host-guest interaction of the prodrug Olsalazine (OLZ) and β-Cyclodextrin (β-CD) was examined experimentally and computationally. Experimentally, employing the UV–Vis spectroscopic method ... -
On the molecular properties of graphene-pyrazines conjugated Ru and Fe complexes: Computational insights
( Elsevier , 2020 , Article)Graphene and related materials can exhibit substantial molecular properties of significant importance in various landscapes of interests including catalysis. On the other hand, transition-metal-based molecular heterogeneous ... -
On the nature of defect states in tungstate nanoflake arrays as promising photoanodes in solar fuel cells
( Royal Society of Chemistry , 2016 , Article)An electrochemical method is presented to study the nature of the defect states in sub-stoichiometric tungsten oxide nanoflake photoanodes used in water splitting. First, stoichiometric/sub-stoichiometric tungstate nanoflake ... -
One‐pot microwave‐assisted synthesis of water‐soluble pyran‐2,4,5‐triol glucose amine schiff base derivative: Xrd/hsa interactions, crystal structure, spectral, thermal and a DFT/TD‐DFT
( MDPI AG , 2021 , Article)The(3R,4R,6R)‐3‐(((E)‐2‐hydroxybenzylidene)amino)‐6‐(hydroxymethyl)tetrahydro‐2H-pyran‐2,4,5‐triol water‐soluble Glucose amine Schiff base (GASB‐1) product was made available by condensation of 2‐hydroxybenzaldehyde with ... -
Optical and electrical properties of a new polymer
( John Wiley & Sons, Inc. , 1997 , Article)Thin film of poly (5-isopropylidenecyclo-1,4-vinylene-2,3-dicarboxylicacidamide-s-methyl hydrazinecarbodithioate) (II) (Scheme 1) of 5 μm thickness was prepared. The dielectric properties of the prepared sample were studied ...