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Application of a definitive screening design for the synthesis of a charge-transfer complex of sparfloxacin with tetracyanoethylene: Spectroscopic, thermodynamic, kinetics, and DFT computational studies
( Royal Society of Chemistry , 2019 , Article)Herein, a spectrochemical approach was adopted to study the charge-transfer (CT) complexation of sparfloxacin (SFX) with tetracyanoethylene (TCNE). In this study, a three-level design of experiments (DOE) involving a ... -
Aqueous dispersions of carbon black and its hybrid with carbon nanofibers
( Royal Society of Chemistry , 2018 , Article)The aqueous dispersions of a special type of carbon black (CB) in 1 M lithium bis(trifluoromethanesulfonimide) electrolyte is mainly controlled by the affinity of the aqueous electrolyte towards the CB particles rather ... -
Computational insights into the photocyclization of diclofenac in solution: Effects of halogen and hydrogen bonding
( Royal Society of Chemistry , 2016 , Article)The effects of noncovalent interactions, namely halogen and hydrogen bonding, on the photochemical conversion of the photosensitizing drug diclofenac (DCF) in solution were investigated computationally. Both explicit and ... -
Controlled design of PtPd nanodendrite ornamented niobium oxynitride nanosheets for solar-driven water splitting
( Royal Society of Chemistry , 2018 , Article)Developing efficient photocatalysts for the water splitting reaction is crucial in a fuel cell reaction. Herein, we present a facile road-map for one-pot fabrication of PtPd nanodendrite (ND) ornamented niobium oxynitride ... -
Curcumin a Colorimetric and Fluorimetric Cyanide Probe in Aqueous System and Living Cells
( Royal Society of Chemistry , 2019 , Article)Curcumin, 1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-hepta-diene-3,5-dione, is a natural product obtained from the rhizome of Curcuma longa. Curcumin has been demonstrated to be a strong antioxidant with anticancer properties ... -
Effect of silylating agents on the superhydrophobic and self-cleaning properties of siloxane/polydimethylsiloxane nanocomposite coatings on cellulosic fabric filters for oil-water separation
( Royal Society of Chemistry , 2021 , Article)A new facile approach for preparing two nonfluorinated hybrid organic-inorganic siloxane/polydimethylsiloxane nanocomposite coatings for cotton fabrics is presented using two distinct silylating agents. The first coated ... -
Enhanced photocatalytic performance of WON@porous TiO2 nanofibers towards sunlight-assisted degradation of organic contaminants
( Royal Society of Chemistry , 2018 , Article)In the last few decades, TiO2 has been widely used in different types of photocatalytic applications. However, the relatively large optical band gap (∼3.2 eV), low charge carrier mobility and consequently its low quantum ... -
Highly active, durable and pH-universal hybrid oxide nanocrystals for efficient oxygen evolution
( Royal Society of Chemistry , 2017 , Article)The development of an active, durable, and low-cost catalyst remains hitherto a grand challenge in energy conversion technologies. Herein, hybrid Ptx-NiMnO3 nanocrystals (NCs) (x = 0.1, 0.5, and 1.0 mM) were synthesized ... -
Influence of the heteroatom on the optoelectronic properties and transistor performance of soluble thiophene-, selenophene- and tellurophene-vinylene copolymers
( Royal Society of Chemistry , 2016 , Article)We report the first soluble poly(3-dodecyl tellurophenylene-vinylene) polymer (P3TeV) by Stille copolymerization and compare its properties to the analogous thiophene and selenophene containing polymers. The optical band ... -
Interaction of: P -synephrine with p -chloranil: Experimental design and multiple response optimization
( Royal Society of Chemistry , 2016 , Article)© 2016 The Royal Society of Chemistry. In the current paper, and for the first time, spectrophotometry coupled with a set of factorial designs was executed as a new tool for investigating the interaction between p-synephrine ... -
Interaction of: P -synephrine with p -chloranil: Experimental design and multiple response optimization
( Royal Society of Chemistry , 2016 , Article)In the current paper, and for the first time, spectrophotometry coupled with a set of factorial designs was executed as a new tool for investigating the interaction between p-synephrine (p-SY) and p-chloranil (p-CHL). Two ... -
Mechanochemical arylative detrifluoromethylation of trifluoromethylarenes
( Royal Society of Chemistry , 2023 , Article)The stoichiometric defluorinative functionalization of ArCF3 is a conceptually appealing research target. It enables the challenging late-stage functionalization of CF3-containing aromatic molecules and contributes to the ... -
Natural clay-supported palladium catalysts for methane oxidation reaction: Effect of alloying
( Royal Society of Chemistry , 2019 , Article)The catalytic combustion of methane (CCM) has been extensively studied owing to the wide use of methane in motor vehicles and power generation turbines. However, the absence of polarizability and the high C-H bond strength ... -
On the nature of defect states in tungstate nanoflake arrays as promising photoanodes in solar fuel cells
( Royal Society of Chemistry , 2016 , Article)An electrochemical method is presented to study the nature of the defect states in sub-stoichiometric tungsten oxide nanoflake photoanodes used in water splitting. First, stoichiometric/sub-stoichiometric tungstate nanoflake ... -
Porous dendritic BiSn electrocatalysts for hydrogenation of 5-hydroxymethylfurfural
( Royal Society of Chemistry , 2022 , Article)The electrocatalytic hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (BHMF) is an alternative to conventional heterogeneous catalysis with H2 at high temperatures and pressures. Although Ag ... -
Rational design of porous binary Pt-based nanodendrites as efficient catalysts for direct glucose fuel cells over a wide pH range
( Royal Society of Chemistry , 2017 , Article)The development of porous bi-metallic Pt-based nanocrystals (NCs) as efficient catalysts for the glucose oxidation reaction (GOR) over a wide pH range is still a grand challenge. Triggered by this challenge, we report the ... -
Rational one-step synthesis of porous PtPdRu nanodendrites for ethanol oxidation reaction with a superior tolerance for CO-poisoning
( Royal Society of Chemistry , 2017 , Article)Precise fabrication of porous ternary Pt-based nanodendrites is very important for electrochemical energy conversion owing to high surface area and great molecular accessibility of these nanodendrites. Herein, PtPdRu porous ... -
Self-assembled zirconia nanotube arrays: Fabrication mechanism, energy consideration and optical activity
( Royal Society of Chemistry , 2014 , Article)We present a comprehensive roadmap for the precise control of the dimensions and optical properties of anodically fabricated zirconia nanotubes. The effects of anodization time, applied voltage, solvent composition, as ... -
Solution combustion synthesis of Ni/La2O3for dry reforming of methane: Tuning the basicity via alkali and alkaline earth metal oxide promoters
( Royal Society of Chemistry , 2021 , Article)The production of syngas via dry reforming of methane (DRM) has drawn tremendous research interest, ascribed to its remarkable economic and environmental impacts. Herein, we report the synthesis of K, Na, Cs, Li, and ... -
Suspensions of carbon nanofibers in organic medium: Rheo-electrical properties
( Royal Society of Chemistry , 2015 , Article)The nonaqueous suspensions of carbon nanofibers (CNFs) in 1 M lithium bis(trifluoromethanesulfonaimide) in propylene carbonate electrolyte reveal unique structural evolution and shear-induced transition due to the high ...