Energy and exergy analysis of parallel flow double effect H2O-[mmim][DMP] absorption refrigeration system for solar powered district cooling

Abstract

Solar thermal energy-driven double effect absorption refrigeration system (DE-ARS) for district cooling in smart cities is an efficient, and sustainable alternative for centralized air conditioning and concurrently harnesses low-grade solar energy. This work investigates ionic liquid based H2O-[mmim][DMP] mixture as an alternative working fluid to overcome the drawback of H2O–LiBr driven DE-ARS. The thermodynamic properties of H2O-[mmim][DMP] mixture is evaluated using the excess Gibbs free energy model. Performance modeling and simulation of DEARS is based on both energy and exergy analysis by applying the first and second laws of thermodynamic. The performance, and solution circulation ratio of parallel flow DE-ARS is assessed and optimized under various temperatures and solution distribution ratios. In comparison to the conventional H2O–LiBr, the proposed H2O-[mmim][DMP] working fluid achieves 5.22% and 4.95% improvement in COP and ECOP, respectively at Th/Te/Ta/Tc of 140/5/30/30◦C . An optimization of generator temperature to achieve maximum COP and ECOP is performed for a wide range of evaporation temperature from 5 to 20◦C and Ta/Tc from 30 to 40◦C. An optimization of H2O-[mmim][DMP] mixture driven DE-ARS reveals the uppermost COPmax and ECOPmax of 1.81 and 0.69 for Te of 20◦C and Ta––Tc=30◦C.