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AuthorAlQaradawi, Siham Y.
AuthorNour, E.M.
Available date2017-02-16T10:26:04Z
Publication Date2006-08-07
Publication NameJournal of Molecular Structureen_US
Identifierhttp://dx.doi.org/10.1016/j.molstruc.2006.02.031
CitationSiham Y. AlQaradawi, E.M. Nour, "Synthesis and spectroscopic structural studies of the adducts formed in the reaction of aminopyridines with TCNQ," Journal of Molecular Structure, Volume 794, Issues 1–3, 7 August 2006, Pages 251-254
ISSN00222860
URIhttp://www.sciencedirect.com/science/article/pii/S0022286006002043
URIhttp://hdl.handle.net/10576/5263
AbstractThe adducts 7,7-dicyano-8,8-di-m-aminopyridilequinodimethane and 7,7-dicyano-8,8-di-p-aminopyridilequinodimethane are formed by the reaction of the electron donors 3-aminopyridine (3APY) and 4-aminopyridine (4APY), respectively, with the π-acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ). The reactions were studied using electronic, infrared and mass spectral and thermal measurements. The results indicate that the aminopyridines undergo rapid N-substitution by TCNQ forming the reaction products and HCN molecules. A general mechanism for the reactions as well as the structures of the reaction products are proposed.
Languageen
PublisherElsevier
SubjectAminopyridines
SubjectTCNQ
SubjectSpectra
SubjectThermal
TitleSynthesis and spectroscopic structural studies of the adducts formed in the reaction of aminopyridines with TCNQ
TypeArticle
Pagination251-254
Issue Number1
Volume Number794


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