ZnO@C (core@shell) microspheres derived from spent coffee grounds as applicable non-precious electrode material for DMFCs
المؤلف | Ghouri, Zafar Khan |
المؤلف | Al-Meer, Saeed |
المؤلف | Barakat, Nasser A. M. |
المؤلف | Kim, Hak Yong |
تاريخ الإتاحة | 2017-05-14T11:33:53Z |
تاريخ النشر | 2017-05-11 |
اسم المنشور | Scientific Reports |
المعرّف | http://dx.doi.org/10.1038/s41598-017-01463-3 |
الاقتباس | Ghouri, Zafar Khan., Al-Meer, Saeed., Barakat, Nasser A. M., Kim, Hak Yong., ZnO@C (core@shell) microspheres derived from spent coffee grounds as applicable non-precious electrode material for DMFCs, Scientific Reports, 7:1738, 2017, DOI:10.1038/s41598-017-01463-3 |
الرقم المعياري الدولي للكتاب | 2045-2322 |
المعرّف | Article number: 1738 |
الملخص | Although numerous reports have introduced non precious electrocatalysts for methanol oxidation, most of those studies did not consider the corresponding high onset potential which restricts utilization in real fuel cells. In this study, an −90 mV [vs. Ag/AgCl] onset potential non-precious electrocatalyst is introduced as an applicable anode material for the direct methanol fuel cells. Moreover, the proposed material was prepared from a cheap and abundantly existing resource; the spent coffee grounds. Typically, the spent coffee grounds were facilely converted to core@shell (ZnO@C) microspheres through a two-step approach, involving chemical activation and a subsequent calcination at temperature of 700 °C. Activation of the carbon derived from the spent coffee grounds was performed with ZnCl2 which acts as pore-forming agent as well as a precursor for the ZnO. The structure and morphology were characterized by (XRD), (SEM), and (TEM) analyses while the electrochemical characterizations was evaluated by cyclic voltammetry (CV) technique. Besides the comparatively very low onset potential, the introduced microspheres exhibited relatively high current density; 17 mA/cm2. Overall, based on the advantages of the green source of carbon and the good electrocatalytic activity, the spent coffee grounds-derived carbon can be considered a promise anode material for the DMFCs. |
راعي المشروع | This Publication was made possible by NPRP grant # [8-1344-1-246] from the Qatar National Research Fund (a member of Qatar Foundation). The findings achieved herein are solely the responsibility of authors. |
اللغة | en |
الناشر | Nature Publishing Group |
الموضوع | ZnO@C Fuel cells Energy science and technology DMFCs |
النوع | Article |
رقم المجلد | 7 |
ESSN | 2045-2322 |
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