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AuthorKaruppasamy, K.
AuthorVikraman, Dhanasekaran
AuthorHussain, Sajjad
AuthorThirumalraj, Balamurugan
AuthorSanthoshkumar, P.
AuthorParangusan, Hemalatha
AuthorPark, Hyun-Chang
AuthorJung, Jongwan
AuthorKim, Hyun-Seok
Available date2024-07-16T06:15:13Z
Publication Date2023
Publication NameJournal of Energy Chemistry
ResourceScopus
Identifierhttp://dx.doi.org/10.1016/j.jechem.2023.01.005
ISSN20954956
URIhttp://hdl.handle.net/10576/56693
AbstractExploring novel versatile electrode materials with outstanding electrochemical performance is the key to the development of advanced energy conversion and storage devices. In this work, we aim to construct new-fangled one-dimensional (1D) quasi-layered patronite vanadium tetrasulfide (VS4) nanostructures by using different sulfur sources, namely thiourea, thioacetamide, and L-cysteine through an ethyleneaminetetraacetic-acid (EDTA)-mediated solvothermal process. The as-prepared VS4 exhibits several unique morphologies such as urchin, fluffy nanoflower, and polyhedron with appropriate surface areas. Among the prepared nanostructures, the VS4-1@NF nanostructure exhibited excellent electrochemical properties in 6 M KOH solution, and we explored its redox electrochemistry in detail. The as-prepared VS4-1@NF electrode exhibited battery-type redox characteristics with the highest capacity of 280 C g-1 in a three-electrode assembly. Moreover, it offered a capacity of 123 F g-1 in a hybrid two-electrode set-up at 1 A g-1 with the highest specific energy and specific power of 38.5 W h kg-1 and 750 W kg-1, respectively. Furthermore, to ensure the practical applicability and real-world performance of the prepared hybrid AC@NF//VS4-1@NF cell, we performed a cycling stability test with more than 5,000 galvanostatic charge-discharge cycles at 2 A g-1, and the cell retained around 84.7% of its capacitance even after 5,000 cycles with a CE of 96.1%.
SponsorThis work was supported by the Research Program of Dongguk University in 2022 (No. S-2022-G0001-00016).
Languageen
PublisherElsevier
Subject1D material
Mesoporous
Patronite
Redox electrochemistry
Urchin VS4
TitleUnveiling the redox electrochemistry of 1D, urchin-like vanadium sulfide electrodes for high-performance hybrid supercapacitors
TypeArticle
Pagination569-580
Volume Number79
dc.accessType Abstract Only


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