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المؤلفMonai, Matteo
المؤلفMontini, Tiziano
المؤلفMelchionna, Michele
المؤلفDuchon, Tomas
المؤلفKus, Peter
المؤلفChen, Chen
المؤلفTsud, Nataliya
المؤلفNasi, Lucia
المؤلفPrince, Kevin C.
المؤلفVeltruska, Katerina
المؤلفMatolin, Vladimir
المؤلفKhader, Mahmoud M.
المؤلفGorte, Raymond J.
المؤلفFornasiero, Paolo
تاريخ الإتاحة2021-02-08T09:14:52Z
تاريخ النشر2017
اسم المنشورApplied Catalysis B: Environmental
المصدرScopus
معرّف المصادر الموحدhttp://dx.doi.org/10.1016/j.apcatb.2016.09.016
معرّف المصادر الموحدhttp://hdl.handle.net/10576/17582
الملخصSO2 poisoning of methane oxidation over alumina-supported, Pd@CexZr1−xO2 nanoparticle catalysts was systematically studied by means of advanced PhotoElectron Spectroscopy (PES) methods. The Pd@CexZr1−xO2 units were synthesized and deposited on two modified-alumina supports, i.e. high surface area modified alumina and a model alumina prepared by Atomic Layer Deposition (ALD) of alumina on Indium Tin Oxide (ITO)/quartz slides. The model support was designed to be suitable for PES analysis and was stable to high temperature treatments (850 °C). Characterization of the high-surface-area (HSA) catalysts by X-Ray Diffraction (XRD), N2 physisorption, CO chemisorption and Transmission Electron Microscopy (TEM) indicated formation of CeO2–ZrO2 (CZ) mixed-oxide crystallites that stabilize the Pd active phase against sintering. Correlation of methane-oxidation rates with PES results demonstrated two distinct mechanisms for deactivation by SO2. Below 450 °C, the presence of SO2 in the feed led to partial reduction of the active PdO phase and to the formation of sulfates on the Pd. Above 500 °C, poisoning by SO2 was less severe due to spillover of the sulfates onto the oxide promoter. Pd@ZrO2 catalysts showed the best resistance to SO2 poisoning, outperforming analogous Pd@CZ mixed-oxide catalysts, because there was less sulfate formation and the sulfates that did form could be removed during regeneration.
راعي المشروعThe authors acknowledge CERIC-ERIC for open access to instrumentation and user support. This paper was also made possible by a NPRP Grant #6-290-1-059 from the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are solely the responsibility of the authors.
اللغةen
الناشرElsevier B.V.
الموضوعCeria-Zirconia
Methane oxidation catalysts
Palladium
Sulfur dioxide
XPS
العنوانThe effect of sulfur dioxide on the activity of hierarchical Pd-based catalysts in methane combustion
النوعArticle
الصفحات72-83
رقم المجلد202
dc.accessType Abstract Only


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