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AuthorPatel, Hasmukh A.
AuthorKaradas, Ferdi
AuthorCanlier, Ali
AuthorPark, Joonho
AuthorDeniz, Erhan
AuthorJung, Yousung
AuthorAtilhan, Mert
AuthorYavuz, Cafer T.
Available date2023-02-22T10:05:14Z
Publication Date2012
Publication NameJournal of Materials Chemistry
ResourceScopus
URIhttp://dx.doi.org/10.1039/c2jm30761h
URIhttp://hdl.handle.net/10576/40288
AbstractEfficient CO2 scrubbing without a significant energy penalty remains an outstanding challenge for the fossil fuel-burning industry where aqueous amine solutions are still widely used. Porous materials have long been evaluated for next generation CO2 adsorbents. Porous polymers, robust and inexpensive, show promise as feasible materials for the capture of CO2 from warm exhaust fumes. We report the syntheses of porous covalent organic polymers (COPs) with CO2 adsorption capacities of up to 5616 mg g−1 (measured at high pressures, i.e. 200 bar) and industrially relevant temperatures (as warm as 65 °C). COPs are stable in boiling water for at least one week and near infinite CO2/H2 selectivity is observed.
Languageen
PublisherRoyal Society of Chemistry
SubjectAdsorption capacities
Amine solutions
Boiling water
Carbon dioxide adsorption
TitleHigh capacity carbon dioxide adsorption by inexpensive covalent organic polymers
TypeArticle
Pagination8431-8437
Issue Number17
Volume Number22
dc.accessType Abstract Only


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