Show simple item record

AuthorKhan, Muhammad Imran
AuthorShanableh, Abdallah
AuthorKhraisheh, Majeda
AuthorAlmomani, Fares
Available date2023-04-03T09:16:28Z
Publication Date2022-01-16
Publication NameMembranes
Identifierhttp://dx.doi.org/10.3390/membranes12010095
CitationKhan, M. I., Shanableh, A., Khraisheh, M., & AlMomani, F. (2022). Synthesis of porous BPPO-based anion exchange membranes for acid recovery via diffusion dialysis. Membranes, 12(1), 95.
ISSN2077-0375
URIhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85126067494&origin=inward
URIhttp://hdl.handle.net/10576/41606
AbstractDiffusion dialysis (DD) is an anion exchange membrane-based functional separation process used for acid recovery. TMA (trimethylamine) and BPPO (brominated poly(2,6-dimethyl-1,4-phenylene oxide) were utilized in this manuscript to formulate AEMs (anion exchange membranes) for DD (diffusion dialysis) using the phase-inversion technique. FTIR (Fourier transfer infrared) analysis, proton NMR spectroscopy, morphology, IEC (ion exchange capacity), LER (linear expansion ratio), Cr (fixed group concentration), Wr (water uptake/adsorption), water contact angle, chemical, and thermal stability, were all used to evaluate the prepared membranes. The effect of TMA content within the membrane matrix on acid recovery was also briefly discussed. It was reported that porous AEMs have a Wr of 149.6% to 233.8%, IEC (ion exchange capacity) of 0.71 to 1.43 mmol/g, Cr (fixed group concentration) that ranged from 0.0046 mol/L to 0.0056 mol/L, LER of 3.88% to 9.23%, and a water contact angle of 33.10° to 78.58°. The U∏ (acid dialysis coefficients) for designed porous membranes were found to be 0.0043 to 0.012 m/h, with separation factors (S) ranging from 13.14 to 32.87 at the temperature of 25 °C. These observations are comparable to those found in the DF-120B commercial membrane with U∏ of 0.004 m/h and S of 24.3 m/h at the same temperature (25 ° C). This porous membranes proposed in this paper are excellent choices for acid recovery through the diffusion dialysis process.
SponsorQatar University internal grant # (QUCG-CENG-21/22-4).
Languageen
PublisherMultidisciplinary Digital Publishing Institute (MDPI)
SubjectAcid recovery
BPPO
Diffusion dialysis
Porous anion exchange membrane (AEM)
Trimethylamine
TitleSynthesis of Porous BPPO-Based Anion Exchange Membranes for Acid Recovery via Diffusion Dialysis
TypeArticle
Issue Number1
Volume Number12
ESSN2077-0375
dc.accessType Open Access


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record