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AuthorHijji, Yousef
AuthorButcher, Ray J.
AuthorJasinski, Jerry P.
Available date2024-02-27T09:43:32Z
Publication Date2014-01-01
Publication NameActa Crystallographica Section E: Structure Reports Online
Identifierhttp://dx.doi.org/10.1107/S160053681400871X
CitationHijji, Y., Butcher, R. J., & Jasinski, J. P. (2014). (E)-2-{[4-(Dimethylamino) benzylidene] amino}-5-nitrophenol. Acta Crystallographica Section E: Structure Reports Online, 70(5), o598-o599.‏
URIhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84899897294&origin=inward
URIhttp://hdl.handle.net/10576/52296
AbstractThe title Schiff base compound, C15H15N 3O3, crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the nitro group and its benzene ring is 2.1(2)° and that between the two benzene rings is 0.88(7)°, while the corresponding angles for molecule B are 5.7(1) and 2.45(6)°, respectively. In each molecule, there is an intramolecular O - H⋯N hydrogen bond. In the crystal, inversion-related molecules are linked via O - H⋯O hydrogen bonds forming A-A and B-B dimers. These dimers are linked via C - H⋯O hydrogen bonds involving the nitro O atoms, forming A-A-A and B-B-B slabs that lie parallel to one another and to (010). © 2014 CrossMark.
Languageen
PublisherInternational Union of Crystallography
Subjectdata-to-parameter ratio = 23.1
mean σ(C-C) = 0.002 A°
R factor = 0.041
single-crystal X-ray study
T = 123 K
wR factor = 0.119
Title(E)-2-{[4-(dimethylamino)benzylidene]amino}-5-nitrophenol
TypeArticle
Paginationo598-o599
Issue Number5
Volume Number70
dc.accessType Open Access


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