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AuthorWaware, Umesh S.
AuthorRashid, Mohd
AuthorHamouda, A. M.S.
AuthorAdnan, Rohana
Available date2024-03-07T11:15:09Z
Publication Date2020-03-13
Publication NamePolymer Bulletin
Identifierhttp://dx.doi.org/10.1007/s00289-020-03153-z
CitationWaware, U. S., Rashid, M., Hamouda, A. M. S., & Adnan, R. (2021). Highly crystalline and thermally stable poly (aniline-co-2-nitroaniline). Polymer Bulletin, 78, 1407-1421.
ISSN0170-0839
URIhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85081746823&origin=inward
URIhttp://hdl.handle.net/10576/52806
AbstractAbstract: To synthesize a crystalline polymer is unconventional. Here, we found the well-defined hexagonal or rectangular cubical shape of poly(aniline-co-2-nitroaniline)s PA-co-2-NAs through scanning electron microscopy. Enhanced crystallinity of PA-co-2-NAs has been confirmed by differential scanning calorimetry and particle size analysis. The edge and structural morphology of the material has been studied by SEM and TEM analysis. The physical nature of –NO2 groups and the bandgap between HOMO and LUMO of the copolymer have been evaluated by FTIR and UV–vis spectroscopy, respectively. The overall reduced particle size of A-co-2-NA supports the improved percentage of the crystallinity of the material. The spatial resolutions at nano-level examined through (TEM) also confirm the sharp edges of the material. The diminished electrical conductivity of the copolymer is determined by applying the four-probe method. Graphic abstract: [Figure not available: see fulltext.]
SponsorThis work was financially supported by University Sains Malaysia, and the Qatar University.
Languageen
PublisherSpringer Nature
SubjectEnhanced crystallinity
Higher stability
Improved solubility
Poly(aniline-co-2-nitroaniline)
Reduced particle size
TitleHighly crystalline and thermally stable poly(aniline-co-2-nitroaniline)
TypeArticle
Pagination1407-1421
Issue Number3
Volume Number78
ESSN1436-2449
dc.accessType Full Text


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