Carbon dioxide hydrogenation to value-added products using Cu-based catalytic materials
المؤلف | Ismail, Rim |
المؤلف | Saad, Mohamed Ali H. |
المؤلف | Sardar, Ali |
المؤلف | Benamor, Abdelbaki |
تاريخ الإتاحة | 2024-03-18T06:24:35Z |
تاريخ النشر | 2023 |
اسم المنشور | IOP Conference Series: Earth and Environmental Science |
المصدر | Scopus |
الرقم المعياري الدولي للكتاب | 17551307 |
الملخص | In this work, we report on the synthesis and evaluation of catalytic materials composed of copper/calcium oxide/alumina (Cu/CaO/Al2O3) for carbon dioxide conversion to value-added products. Catalytic materials were synthesized using sequential incipient wetness impregnation method. Synthesized materials with different compositions of copper and adsorbent were tested in a high-pressure packed bed reactor under a pressure P =60 bars, temperature T=300 °C, and hydrogen to carbon dioxide ratio (H2/CO2 = 3) to determine their performances and catalytic activities. The results of the activity revealed that CaO-based catalysts were very active in converting CO2 to methanol and carbon monoxide. Catalyst containing 30%Cu10%CaO achieved the highest CO2 conversion of 16.5% and a maximum methanol selectivity of 17.8%, while the lowest selectivity towards carbon monoxide (CO) were obtained using 20%Cu-containing catalyst. Reducing CaO content from 10wt% to 5wt% boosted the CO2 conversion to 18% with higher selectivity towards CO compared to the catalyst containing 10%CaO. |
راعي المشروع | Financial support for this work was provided by Qatar University through internal grant IRCC-203-2023. |
اللغة | en |
الناشر | Institute of Physics |
الموضوع | Carbon dioxide hydrogenation Cu catalytic materials carbon dioxide conversion |
النوع | Conference |
رقم العدد | 1 |
رقم المجلد | 1281 |
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