Removal of heavy metals from wastewater by aerogel derived from date palm waste

Abstract

Cellulose that has been sourced from date palm leaves as a primary component was utilised. This cellulose served as the foundational material for the development of an aerogel composite. During this process, MXene (Ti3C2Tx) played a pivotal role in enhancing the overall composition of the aerogel. To ensure the stability and durability of the resulting aerogel structure, calcium ions were introduced to the mix. These ions facilitated the cross-linking process of sodium alginate molecules, ultimately leading to the formation of calcium alginate. This cross-linking step is crucial for the enhanced mechanical and chemical stability of the aerogel. Incorporating alginate and Ti3C2Tx into the cellulose aerogel enhanced its structural integrity in aqueous conditions and increased its adsorption capacity. When evaluated with synthetic wastewater, this composite exhibited remarkable adsorption capacities of 72.9, 114.4, 92.9, and 123.9 mg/g for As, Cd, Ni, and Zn ions, respectively. A systematic study was carried out to see the effect of various parameters, including contact time, MXene concentration, pH, and temperature on the adsorption of these elements. Peak adsorption was achieved at 60 min, favoring a pH range between 6 and 8 and exhibited optimal sorption efficiency at lower temperatures. The adsorption kinetics adhered closely to a pseudo-second-order, while the Freundlich model adeptly described the adsorption isotherms. An interesting result of this research was the aerogel's regenerative potential. After undergoing a basic acid treatment, the MXene/cellulose/alginate aerogel composite could be restored and reused for up to three cycles, all while maintaining its core performance capabilities even after the rigorous cross-linking processes. In three consecutive cycles, the removal percentages for As, Cd, Ni, and Zn were 48.15%, 80.38%, 56.51%, and 86.12% in cycle 1; 37.35%, 65.63%, 45.97%, and 78.42% in cycle 2; and 28.60%, 56.22%, 34.70%, and 65.83% in cycle 3, respectively. The composite was tested in conditions resembling seawater salinity. Impressively, the aerogel continued to demonstrate a significant ability to adsorb metals, reinforcing its potential utility in real-world aquatic scenarios. These findings suggest that the composite aerogel, integrating MXene, cellulose, and alginate, is an effective medium for the targeted removal of heavy metals from aquatic environments.