Sustainable Preparation of Graphene Quantum Dots from Leaves of Date Palm Tree

Abstract

The date palm (Phoenix dactylifera), a subtropical and tropical tree, included in the family Palmae (Arecaceae) is one of the oldest cultivated plants of mankind. Date palm is a major agricultural product in the semi-arid and arid areas of the world, particularly in Arab countries. These trees generate high quantities of agricultural waste in the form of dry leaves, seeds, etc. In this study, dried date palm leaves were used as green precursors for synthesizing graphene quantum dots (GQDs). This work reported the preparation of GQDs using two different sustainable methods. GQD-1 was developed using a simple, hydrothermal technique at 200 °C for 12 h in water, with no requirement of reducing or passivizing agents or organic solvents. GQD-2 was prepared using a hydrothermal technique at 200 °C for 12 h in water, with the usage of just distilled water and absolute ethanol. The compositional analysis of the leaf extract was performed, along with the morphological, compositional, and optical examination of the sustainably developed GQDs. The characterization results confirmed the successful formation of GQDs, with average sizes ranging from 3.5 to 8 nm. This study helps to obtain GQDs in an economical, eco-friendly, and biocompatible manner and can assist in large-scale production and in recycling date palm tree waste products from Middle East countries into value-added products.