MXene (Ti3 C2 Tx )/Cellulose Acetate Mixed-Matrix Membrane Enhances Fouling Resistance and Rejection in the Crossflow Filtration Process
Author | Azam, Reem S. |
Author | Almasri, Dema A. |
Author | Alfahel, Radwan |
Author | Hawari, Alaa H. |
Author | Hassan, Mohammad K. |
Author | Elzatahry, Ahmed A. |
Author | Mahmoud, Khaled A. |
Available date | 2023-02-02T04:34:13Z |
Publication Date | 2022 |
Publication Name | Membranes |
Resource | Scopus |
Abstract | Obstacles in the membrane-based separation field are mainly related to membrane fouling. This study involved the synthesis and utilization of covalently crosslinked MXene/cellulose acetate mixed matrix membranes with MXene at different concentrations (CCAM-0% to CCAM-12%) for water purification applications. The membranes' water flux, dye, and protein rejection performances were compared using dead-end (DE) and crossflow (CF) filtration. The fabricated membranes, especially CCAM-10%, exhibited high hydrophilicity, good surface roughness, significantly high water flux, high water uptake, and high porosity. A significantly higher flux was observed in CF filtration relative to DE filtration. Moreover, in CF filtration, the CCAM-10% membrane exhibited 96.60% and 99.49% rejection of methyl green (MG) and bovine serum albumin (BSA), respectively, while maintaining a flux recovery ratio of 67.30% and an irreversible fouling ratio at (Rir ) of 32.70, indicating good antifouling performance. Hence, this study suggests that covalent modification of cellulose acetate membranes with MXene significantly improves the performance and fouling resistance of membranes for water filtration in CF mode relative to DE mode. |
Sponsor | The authors would like to acknowledge the research support provided by HBKU/Qatar Foundation. The authors acknowledge M. Helal and A. R Shetty of QEERI Core Labs for SEM and XRD measurements, respectively. The technical support of R. Pandey and P. Abdul Rasheed is highly appreciated. RA is sponsored by the Graduate Sponsorship Research Award (GSRA7-1-0429-20028) from the Qatar National Research Fund (a member of Qatar Foundation). Open Access funding provided by the Qatar National Library. |
Language | en |
Publisher | MDPI |
Subject | antifouling crossflow membrane filtration MXene |
Type | Article |
Issue Number | 4 |
Volume Number | 12 |
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Center for Advanced Materials Research [1375 items ]
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Civil and Environmental Engineering [850 items ]
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Materials Science & Technology [299 items ]