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المؤلفKhraisheh, Majeda
المؤلفKim, J.
المؤلفCampos, L.
المؤلفAl-Muhtaseb, A.H.
المؤلفWalker, G.M.
المؤلفAlghouti, M.
تاريخ الإتاحة2022-05-21T08:36:55Z
تاريخ النشر2013
اسم المنشورEnvironmental Engineering Science
المصدرScopus
المعرّفhttp://dx.doi.org/10.1089/ees.2012.0056
معرّف المصادر الموحدhttp://hdl.handle.net/10576/31228
الملخصA novel TiO2-coconut shell powder (TCNSP) composite, prepared by the controlled sol-gel method with a subsequent heat treatment, was investigated as an innovative photocatalytic absorbent for the removal of carbamazepine (CBZ). CBZ is used worldwide as an antiepileptic drug, which has recently been recognized as an important organic pollutant increasingly found in wastewaters from urban areas and other aquatic environments. The granulation process was performed by using a semiautomated mass production line to produce sufficient quantities of TCNSP composites, possessing sufficient crush strength for commercialization. Physical properties of the TCNSP composite such as crystallinity, morphology, crush strength, and the Brunauer-Emmett-Teller (BET)-specific surface area were controlled by the mass ratio of titanium dioxide sol and coconut shell powder (CNSP). Calcination at 700 C produced anatase phase TiO2 in the TCNSP composites with a BET high surface area of 454 m2/g. Anatase crystallite size of the TCNSP composite increased from 2.37 to 15.11 nm with increasing calcination temperature from 500 C to 800 C. Calcinated TCNSP composites had higher CBZ removal efficiency (98%) than pure TiO2 (23%) and CNSP (34%) within a 40-min reaction time. Optimization of this innovative adsorption/photocatalytic process was obtained by a response surface methodology and a central composite design model, which indicated that this novel and sustainable technology was successful in removing CBZ from a solution.
اللغةen
الموضوعdrug
granulation
photocatalytic degradation
semiautomated mass production line
TiO2-coconut shell powder composite
العنوانRemoval of carbamazepine from water by a novel TiO2-coconut shell powder/UV process: Composite preparation and photocatalytic activity
النوعArticle
الصفحات515-526
رقم العدد9
رقم المجلد30
dc.accessType Abstract Only


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