Chemistry & Earth Sciences: المرسلات الحديثة
السجلات المعروضة 1 -- 20 من 586
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Network Pharmacology Integrated With Quantum-Polarized Ligand Docking and Molecular Simulation Revealed the Anti-Diabetic Potential of Curcumin
( Wiley , 2024 , Article)Diabetes mellitus is a chronic metabolic disorder affecting millions of people worldwide and causes serious complications such as diabetic nephropathy. Curcumin, a natural polyphenol derived from turmeric, has demonstrated ... -
Exploring the Dynamic Interplay of Deleterious Variants on the RAF1–RAP1A Binding in Cancer: Conformational Analysis, Binding Free Energy, and Essential Dynamics
( Wiley , 2024 , Article)The RAF1–RAP1A interaction activates the MAPK/ERK pathway which is very crucial in the carcinogenesis process. This protein complex influences tumor formation, proliferation, and metastasis. Understanding aberrant interactions ... -
Black Titania Janus Mesoporous Nanomotor for Enhanced Tumor Penetration and Near-Infrared Light-Triggered Photodynamic Therapy
( American Chemical Society , 2024 , Article)Thanks to their excellent photoelectric characteristics to generate cytotoxic reactive oxygen species (ROS) under the light-activation process, TiO2 nanomaterials have shown significant potential in photodynamic therapy ... -
A Synergistic Approach to Develop Sustainable Scale Inhibitors Combining Amino Acids and Polyphosphates
( Springer Nature , 2024 , Article)Applying conventional antiscalants, e.g., polyphosphates, may bring about environmental and health concerns, warranting the application of green compounds. This work reports the application of amino acids such as glutamic ... -
Synthesis and characterization of oxovanadium(IV) urea compound
( Chemical Publishing Co. , 2005 , Article)Vanadyl chloride, VOCl2.6H2O, reacts with urea at room temperature to form the four coordinated oxovanadium(IV) complex of the type [V(O)(urea)2(Cl)2]. The complex is in the mononuclear form where the two urea molecules ... -
Synthesis and spectroscopic studies of metal complexes formed in the reaction of metal ions with urea at high temperature
( Korean Chemical Society , 2007 , Article)Urea reacts with PtCl2, H2[PtCl6]·6H2O, H2[IrCl6] and Ni(CH3CO2)2 in aqueous solution at high temperature (60-80 °C) yielding [PtCl2(Urea)]·2H2O (1), (NH4)2[PtCl6] (2), (NH4)2[IrCl6]·H2O (3) and [Ni2(OH)2(NCO)2(H2O)2] (4) ... -
Spectroscopic studies on the reaction of iodine with the mixed oxygen-nitrogen cyclic base 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8,8,8] hexacosane
( Chemical Publishing Co. , 2005 , Article)The interaction of the mixed oxygen-nitrogen cyclic base, 4,7,13,16,21,24-hexaoxa-1,10- diazabicyclo[8,8,8] hexacosane (HODABCHC) with iodine as a s-acceptor has been studied spectrophotometrically at room temperature in ... -
Vibrational analysis of the trigonal bipyramidal NbCl5 and NbBr5 molecules
( Elsevier , 1986 , Article)Vibrational normal coordinate analysis has been made for NbCl5 and NbBr5 molecules with D3h symmetry and using Wilson's GF matrix method. The observed frequencies are quantitatively assigned on the basis of the calculated ... -
Infrared and Raman studies of [UO2(salen)(L)] (L=H2O and CH3OH)
( Elsevier , 1988 , Article)The infrared and Raman spectra of [UO2(salen)(H2O)] and [UO2(salen)(CH3OH)] (salen=N,N′-ethylenebis(salicylideneimine) have been recorded. Assignments for the fundamental vibrations are proposed on the basis of C2v symmetry ... -
Spectroscopic studies on the uranyl-schiff base solid complex (N,N'-p-phenylenebis(salicylideneiminato)UO2)
( Elsevier , 1992 , Article)The dioxouranium(VI)-Schiff base complex (N,N'-p-phenylenebis(salicylideneiminato)UO2); (UO2(sal-p-phdn)) was prepared. Its resonance Raman, infrared and electronic spectra were obtained and assigned on the basis of C2v ... -
Preparation and infrared spectra of (Cu(O)(H2O)3) and (Cu2(O) (C1)2(H2O)2) complexes formed in the reactions of Cu(II) salts with urea
( Elsevier , 1989 , Article)The preparation and characterization of the new solid complexes (Cu(O)(H2O)3) and (Cu2(O)(Cl)2(H2O)2) formed in the reaction of urea with CuSO4 · 5H2O and CuCl2 · 2H2O, respectively, in aqueous media at ~75°C are reported. ... -
Spectoscopic and structural studies on charge-transfer complexes of lanthanum(III)acetylacetonate with σ-acceptor iodine and π-acceptor DDQ
( Elsevier , 2011 , Article)The interaction of the donor La(III)acetylacetonate, [La(acac)3], with iodine as a r-acceptor and with 2,3- dichloro-5,6 dicyano-1,4-benzoquinone, (DDQ) as a p-acceptor have been studied in the solvents CH2Cl2, CHCl3 and ... -
Vibrational analysis of the (VO(O2)2NH3)- ion
( Elsevier , 1990 , Article)The infrared spectra of the solid complex NH4 (VO(O2)2NH3) were obtained. Due to the complicated structure of the diperoxo (VO(O2)2NH3)− ion, normal coordinate analysis was introduced in order to make quantitative assignments ... -
Synthesis and infrared spectra of alkaline earth metal carbonates formed by the reaction of metal salts with urea at high temperature
( Indian Academy of Sciences , 2004 , Article)The metal carbonate, MCO3 (M = Ca, Sr and Ba), was synthesized by a novel method of reacting aqueous solution of each of Ca2+, Sr2+ and Ba2+ salts with urea at high temperature, ∼ 80°C. The reaction products were characterized ... -
Electronic spectral studies and solvent effects on the reaction of iodine with 1,4,8,11-tetraazacyclotetradecane
( Elsevier , 1988 , Article)The reaction between iodine and 1,4,8,11-tetraazacyclotetradecane (TACTD) is studied photometrically in various solvents like CCl4, CHCl3, CH2Cl2 and 1,2-dichloroethane. The results reveal that in each solvent the (TACTD):I2 ... -
Resonance Raman studies of the peroxotitanate(IV) complexes K2(Ti(O2)(SO4)2).5H2O and K2(Ti(O2)(C2O4)2).3H2O
( Elsevier , 1986 , Article)The resonance Raman spectra of K2(Ti(O2)(SO4)2)·5H2O and K2(Ti(O2)(C2O4)2)·3H2O are recorded. The results are consistent with the triangular structure of the peroxotitanium unit, Ti(O2), with C2ν symmetry. The ν(OO), ... -
Resonance Raman and far-infrared studies of charge-transfer complexes of iodine
( John Wiley and Sons Inc , 1986 , Article)The reactions of I2 with phenazine (PH), acridine (AC) and hexamethylenetetramine (HMTA) have been investigated by resonance Raman and far-infrared spectroscopy. The results indicate that the species (PH)2I+I3−, (AC)2I+I3− ... -
Resonance Raman and far infrared spectroscopic studies of triiodide complexes formed in the reaction of iodine with some polycyclic amines
( Elsevier , 1989 , Article)The solid charge transfer complexes formed in the reaction of iodine with the polycyclic amines 1,4,8,12-tetraazacyclopentadecane (TACPD) and meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (HMTACTD) have ... -
Electronic, infrared, and Raman spectral studies of the reaction of iodine with 4-aminopyridine
( Elsevier , 2005 , Article)The reaction of iodine as an electron acceptor with the base 4-aminopyridine (4APY) has been investigated spectrophotometrically in chloroform at room temperature. The electronic absorptions, infrared and Raman spectra, ... -
Synthesis and Spectroscopic Studies of the Charge‐Transfer Complexes of 2,3‐Diaminopyridine and π‐Electron Acceptors
( Taylor and Francis Ltd. , 2004 , Article)The spectrophotometric properties of the charge transfer (CT)‐complexes formed between 2,3‐diaminopyridine (DAPY) and π‐acceptors tetrachloro‐p‐benzoquinone (chloranil) and tetracyanoethylene (TCNE) have been studied in ...
