Chemistry & Earth Sciences: Recent submissions
Now showing items 141-160 of 586
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Constituents of plants growing in Qatar XX. Phytochemical investigation of anastatica hierochuntica: NOTE
( Taylor & Francis , 1993 , Article)A study of the lipid fraction of Anastatica hierochuntica (Cruciferae) resulted in the isolation of hydrocarbon (mainly C25H52, C29H60 AND C31H64) AND sterol fractions (P-sitosterol, campesterol, stigmasterol AND cholesterol). ... -
Sesquiterpene lactones from Pulicaria sicula
( Elsevier , 1988 , Article)The aerial parts of Pulicaria sicula afforded the known xanthanolides 1-6, the guaianolides 7 and 8 as well as two new ones, the lactone 9 and the corresponding epoxide 10. Furthermore nerylisobutyrate and the thymol ... -
Development of Inorganically Cross-Linked Sulfonated Polyacrylamide Preformed Particle Gels for Conformance Control: Impact of Anionic Groups
( American Chemical Society (ACS) , 2024 , Article)Modern oil and gas extraction faces challenges, notably from the surplus of produced water, hampering hydrocarbon recovery and raising environmental and economic concerns. A promising solution is the injection of preformed ... -
Enhanced adsorptive removal of rifampicin and tigecycline from single system using nano-ceria decorated biochar of mango seed kernel
( Elsevier , 2023 , Article)Pharmaceutically active compounds (PhACs) represent an emerging class of contaminants. With a potential to negatively impact human health and the ecosystem, existence of pharmaceuticals in the aquatic systems is becoming ... -
Metal complex as p-type dopant-based organic spiro-OMeTAD hole-transporting material for free-Li-TFSI perovskite solar cells
( American Institute of Physics , 2024 , Article)Lithium bis(fluorosulfonyl)imide (Li-TFSI) is an efficient p-dopant that has been used to enhance the conductivity of perovskite solar cells (PSCs). However, the performance of the corresponding devices is still not ... -
Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions
( American Chemical Society (ACS) , 2015 , Article)Two new pentadentate {N5} donor ligands based on the N4Py (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) framework have been synthesized, viz. [N-(1-methyl-2-benzimidazolyl)methyl-N-(2-pyridyl)methyl-N-(bi ... -
Catalytic C-H oxidations by nonheme mononuclear Fe(II) complexes of two pentadentate ligands: Evidence for an Fe(IV) oxo intermediate
( Elsevier , 2016 , Article)The oxidation reactions of alkanes with hydrogen peroxide and peracids (peracetic acid (PAA) and m-chloroperoxybenzoic acid (mCPBA)) catalysed by two Fe(II) complexes of pentadentate {N5}-donor ligands have been investigated. ... -
One‐pot microwave‐assisted synthesis of water‐soluble pyran‐2,4,5‐triol glucose amine schiff base derivative: Xrd/hsa interactions, crystal structure, spectral, thermal and a DFT/TD‐DFT
( MDPI AG , 2021 , Article)The(3R,4R,6R)‐3‐(((E)‐2‐hydroxybenzylidene)amino)‐6‐(hydroxymethyl)tetrahydro‐2H-pyran‐2,4,5‐triol water‐soluble Glucose amine Schiff base (GASB‐1) product was made available by condensation of 2‐hydroxybenzaldehyde with ... -
Crystal structure, spectral, thermal and experimental/computational investigation of Anthracen-benzo[d]thiazol-2-amine new Schiff base derivative
( Elsevier B.V. , 2021 , Article)The N-S-N-tridentate ((E)-N-(anthracen-9-ylmethylene)benzo[d]thiazol-2-amine product was made available by dehydration of 2-Aminobenzothiazole with 9-anthraldehyde under non-classical microwave condition, five-minute ... -
(E)-2-{[4-(dimethylamino)benzylidene]amino}-5-nitrophenol
( International Union of Crystallography , 2014 , Article)The title Schiff base compound, C15H15N 3O3, crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in ... -
A Novel Green Synthesis of Thalidomide and Analogs
( Hindawi Limited , 2017 , Article)Thalidomide and its derivatives are currently under investigation for their antiangiogenic, immunomodulative, and anticancer properties. Current methods used to synthesize these compounds involve multiple steps and extensive ... -
Crystal structure of the thalidomide analog (3aR∗,7aS∗)-2-(2,6-dioxopiperidin-3-yl)hexahydro-1H-isoindole-1,3(2H)-dione
( International Union of Crystallography , 2018 , Article)The title compound, C13H16N2O4, crystallizes in the monoclinic centrosymmetric space group, P21/c, with four molecules in the asymmetric unit, thus there is no crystallographically imposed symmetry and it is a racemic ... -
A Comparison between Different Agro-wastes and Carbon Nanotubes for Removal of Sarafloxacin from Wastewater: Kinetics and Equilibrium Studies
( Multidisciplinary Digital Publishing Institute (MDPI) , 2020 , Article)In the current study, eco-structured and efficient removal of the veterinary fluoroquinolone antibiotic sarafloxacin (SARA) from wastewater has been explored. The adsorptive power of four agro-wastes (AWs) derived from ... -
Regulatory Mechanisms That Guide the Fetal to Postnatal Transition of Cardiomyocytes
( Multidisciplinary Digital Publishing Institute (MDPI) , 2023 , Article)Heart disease remains a global leading cause of death and disability, necessitating a comprehensive understanding of the heart’s development, repair, and dysfunction. This review surveys recent discoveries that explore the ... -
Mechanochemical arylative detrifluoromethylation of trifluoromethylarenes
( Royal Society of Chemistry , 2023 , Article)The stoichiometric defluorinative functionalization of ArCF3 is a conceptually appealing research target. It enables the challenging late-stage functionalization of CF3-containing aromatic molecules and contributes to the ... -
Experimental and theoretical investigations of the effect of bis-phenylurea-based aliphatic amine derivative as an efficient green corrosion inhibitor for carbon steel in HCl solution
( Elsevier , 2023 , Article)A novel bis-phenylurea-based aliphatic amine (BPUA) was prepared via a facile synthetic route, and evaluated as a potential green organic corrosion inhibitor for carbon steel in 1.0 M HCl solutions. NMR spectroscopy ... -
Spectrofluorometric investigations on the solvent effects on the photocyclization reaction of diclofenac
( Elsevier , 2023 , Article)The solvent effects on the photochemical conversion rate of the photosensitizing drug diclofenac (DCF) were investigated using steady-state fluorescence spectroscopy. The spectral information obtained for the photochemical ... -
l-Proline-Catalyzed Three-Component Reaction of 4-Chloro-3-formylcoumarin, Sodium Sulfide, and α-Halo Ketones: A Direct Approach to Thieno[3,2- c ]coumarins
( Georg Thieme Verlag KG , 2023 , Article)A new protocol for the synthesis of thieno[3,2-c]coumarins is disclosed. In this method, a 3-formyl-2-oxo-2H-chromene-4-thiolate anion is generated in situ by treatment of 4-chloro-3-formylcoumarin with sodium sulfide. ... -
Uv-l/sulfite advanced reduction process as an efficient method for chlorate reduction in water
( Desalination Publications , 2021 , Article)The efficient reduction of disinfection by-products (DBPs) is currently a major challenge in water treatment facilities due to their high toxicity to human health and long-time residence in the environment. In this work, ... -
Lignin and lignocellulosic materials: A glance on the current opportunities for energy and sustainability
( Springer International Publishing , 2021 , Book chapter)Fossil fuels are running out fast. The energy demand is one of the largest challenges humankind has ever faced. Applications targeting renewable resources that are nonpetroleum based are booming. The scientific community ...
