Chemistry & Earth Sciences: Recent submissions
Now showing items 321-340 of 601
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Antimicrobial Modification of LDPE Using Non-thermal Plasma
( Hamad bin Khalifa University Press (HBKU Press) , 2016 , Conference)Low-density polyethylene (LDPE) represents polymer having good chemical and physical characteristics for which it is widely used in many applications, such as biomedical and food packaging industry. This polymer excels by ... -
Synthesis and Characterization of Soluble Thiophene-Selenophene- and Tellurophene-Vinylene Copolymers
( Hamad bin Khalifa University Press (HBKU Press) , 2016 , Conference)Organic electronic devices based on polymers received significant attention in the last decade, especially for organic photovoltaics (OPVs) and field-effect transistors (OFETs) despite their performances and stability ... -
Piezoelectric properties of zinc oxide/iron oxide filled polyvinylidene fluoride nanocomposite fibers
( Springer , 2021 , Article)Piezoelectric nanogenerators (PENG) with flexible and simple design have pronounced significance in fabricating sustainable devices for self-powering electronics. This study demonstrates the fabrication of electrospun ... -
Core-shell nanofibers of polyvinylidene fluoride-based nanocomposites as piezoelectric nanogenerators
( MDPI AG , 2020 , Article)Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a ... -
Solvent Influence on Absorption Spectra and Tautomeric Equilibria of Symmetric Azomethine-Functionalized Derivatives: Structural Elucidation and Computational Studies.
( Wiley Open Access , 2022 , Article)A new series of azomethine-functionalized compounds was synthesized from the condensation of 2-hydroxy-1,3-propanediamine and 2-thienylcarboxaldehydes in the presence of a drying agent. The derivatives were spectroscopically ... -
Addressing scale-up challenges and enhancement in performance of hydrogen-producing microbial electrolysis cell through electrode modifications
( Elsevier , 2022 , Article Review)Bioelectrohydrogenesis using a microbial electrolysis cell (MEC) is a promising technology for simultaneous hydrogen production and wastewater treatment which uses electrogenic microbes. Microbial activity at the anode and ... -
A Novel Cyclopentadienone and its Ruthenium and Iron Tricarbonyl Complexes
( Wiley , 2021 , Article)A simple and efficient protocol allows the oxidation of the cyclopentadiene derivative 5H-dibenzo[e,h]-dibenzo[3,4 : 6,7]cyclohept[1,2-a]azulene (CpCH) provide according ketone CpCO. Comparable to the situation found for ... -
Further Biochemical Profiling of Metabolome Reveals Its Chemogenetic Diversity
( PMC , 2021 , Article)Natural products with novel chemistry are urgently needed to battle the continued increase in microbial drug resistance. Mushroom-forming fungi are underutilized as a source of novel antibiotics in the literature due to ... -
Synthesis, characterization, surface analysis, optical activity and solvent effects on the electronic absorptions of Schiff base-functionalized amino thiophene derivatives: Experimental and TD-DFT investigations
( Elsevier , 2021 , Article)New derivatives of 3,3′-di-(((E)-(5-substituted-thiophen-2-yl)methylene)amino)-N-methylpropylamines (3a,b) were synthesized from the dehydration of N-methyl-diaminopropylamine and 2-thielylcarboxaldehyde derivatives; ... -
New tetradentate Schiff base Cu(II) complexes: synthesis, physicochemical, chromotropism, fluorescence, thermal, and selective catalytic oxidation
( Springer , 2021 , Article)Three neutral Cu(II)/ƞ4-NNNO Schiff base complexes (1-3) were prepared from the (E)-4-nitro-2-(((2-(piperazin-1-yl)ethyl)imino)methyl)phenol, tetradentate Schiff base (SB) ligand, and the corresponding copper(II) salts. ... -
XRD/HSA, noncovalent interactions and influence of solvent polarity on spectral properties of dithiocarbazate schiff base and its cis-Cu(II) complex: Experimental and theoretical studies
( Elsevier , 2021 , Article)A N,S-bidentate ligand (LH) was synthesized via the condensation of S-benzyldithiocarbazate with acetophenone. The produced Schiff base ligand was reacted with a copper(II) salt to yield a neutral cis-Cu(II) complex. The ... -
Synthesis and Application of Cobalt Oxide (Co3O4)-Impregnated Olive Stones Biochar for the Removal of Rifampicin and Tigecycline: Multivariate Controlled Performance
( MDPI , 2022 , Article)Cobalt oxide (Co3O4) nanoparticles supported on olive stone biochar (OSBC) was used as an efficient sorbent for rifampicin (RIFM) and tigecycline (TIGC) from wastewater. Thermal stabilities, morphologies, textures, and ... -
Application of Samarium- and Terbium-Sensitized Luminescence via a Multivariate-Based Approach for the Determination of Orbifloxacin
( Hindawi , 2022 , Article)A lanthanide-based optical sensor has been developed for the sensitive and reliable spectrofluorometric determination of the fluoroquinolone antibiotic orbifloxacin (ORLX). Reaction of ORLX and two lanthanide metal ions, ... -
Determination of total flavonoid content by aluminum chloride assay: A critical evaluation
( Elsevier , 2021 , Article)Flavonoids are important natural bioactive compounds. Quantitation of total flavonoid content (TFC) is widely performed using the aluminum chloride colorimetric assay against a flavonoid standard assuming equal responses ... -
Indacenodithiazole-Ladder-Type Bridged Di(thiophene)-Difluoro-Benzothiadiazole-Conjugated Copolymers as Ambipolar Organic Field-Effect Transistors
( ACS Publications , 2019 , Article)A series of four donor-acceptor conjugated copolymers P1-P4 with linear and branched side chains based on a ladder-type indacenodithiazole (IDTz) moiety containing an electron-deficient thiazole unit are copolymerized with ... -
Continuous adsorptive removal of glimepiride using multi-walled carbon nanotubes in fixed-bed column.
( Springer , 2021 , Article)Water pollution by emerging pollutants such as pharmaceutical and personal care products is one of today's biggest challenges. The presence of these emerging contaminants in water has raised increasing concern due to their ... -
Synthesis of novel Cubane [Ni4(O∩O)4(OCH3)4(OOH)4] cluster: XRD/HSA-interactions, spectral, DNA-binding, docking and subsequent thermolysis to NiO nanocrystals
( Elsevier , 2020 , Article)Under liquid-state vibration ultrasonic mode, the Ni4(O∩O)4(OCH3)4(OOH)4 complex [O∩O-bidentate ligand = 4,4,4-trifluoro-1-phenylbutane-1,3-dione] was synthesized from metal precursor and ligand in 10% H2O2/MeOH media, as ... -
Solution combustion synthesis of Ni-based hybrid metal oxides for oxygen evolution reaction in alkaline medium
( The Royal Society of Chemistry , 2022 , Article)Oxygen evolution reaction (OER) has arisen as an outstanding technology for energy generation, conversion, and storage. Herein, we investigated the synthesis of nickel-based hybrid metal oxides (NixM1−xOy) and their catalytic ... -
Microwave-assisted palladium-catalyzed cross-coupling reactions: Generation of carbon-carbon bond
( MDPI , 2020 , Article Review)Cross-coupling reactions furnishing carbon–carbon (C–C) bond is one of the most challenging tasks in organic syntheses. The early developed reaction protocols by Negishi, Heck, Kumada, Sonogashira, Stille, Suzuki, and ... -
Synthesis of Novel Aqua ƞ4-NNNO/Cu(II) Complexes as Rapid and Selective Oxidative Catalysts for O-Catechol: Fluorescence, Spectral, Chromotropism and Thermal Analyses
( MDPI , 2021 , Article)A new tetradentate Schiff base (SB), (E)-4-fluoro-2-(1-((2-(piperazin-1-yl)ethyl)imino)ethyl)phe-nol, was synthesized from condensation of 2-(1-piperazinyl)ethylamine and 5-fluoro-2-hydroxyacetophe-none. This ligand was ...