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المؤلفShahzad, Khuram
المؤلفSliem, Mostafa H.
المؤلفShakoor, R. A.
المؤلفRadwan, A. Bahgat
المؤلفKahraman, Ramazan
المؤلفUmer, Malik Adeel
المؤلفManzoor, Umair
المؤلفAbdullah, Aboubakr M.
تاريخ الإتاحة2022-09-28T09:04:27Z
تاريخ النشر2020-12-01
اسم المنشورScientific Reports
المعرّفhttp://dx.doi.org/10.1038/s41598-020-61139-3
الاقتباسShahzad, K., Sliem, M. H., Shakoor, R. A., Radwan, A. B., Kahraman, R., Umer, M. A., ... & Abdullah, A. M. (2020). Electrochemical and thermodynamic study on the corrosion performance of API X120 steel in 3.5% NaCl solution. Scientific reports, 10(1), 1-15.‏
معرّف المصادر الموحدhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85081561794&origin=inward
معرّف المصادر الموحدhttp://hdl.handle.net/10576/34577
الملخصThe present work studied the effect of temperature on the corrosion behavior of API X120 steel in a saline solution saturated with CO2 in absence and presence of polyethyleneimine (PEI) as an environmentally safe green inhibitor. The effect of PEI on the corrosion behavior of API X120 steel was investigated using destructive and non-destructive electrochemical techniques. The overall results revealed that PEI significantly decreases the corrosion rate of API X120 steel with inhibition efficiency of 94% at a concentration of 100 μmol L−1. The adsorption isotherm, activation energy and the thermodynamic parameters were deduced from the electrochemical results. It is revealed that the adsorption of PEI on API X120 steel surface follows Langmuir adsorption isotherm adopting a Physi-chemisorption mechanism. Finally, the samples were characterized using scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques to elucidate the effect of aggressiveness of corrosive media on the surface morphology and the corrosion performance of API X120 steel. The surface topography result indicates that the API X120 steel interface in PEI presence is smoother than CO2 with Cl− ions or Cl− ions only. This is attributed to the compact protective film limits the aggressive ions transfer towards the metallic surface and reduces the corrosion rate. Moreover, PEI inhibition mechanism is based on its CO2 capturing ability and the PEI adsorption on the steel surface beside the siderite layer which give the PEI molecules the ability to reduce the scale formation and increase the corrosion protection due to capturing the CO2 from the brine solution.
اللغةen
الناشرNature Research
الموضوعcorrosion behavior
العنوانElectrochemical and thermodynamic study on the corrosion performance of API X120 steel in 3.5% NaCl solution
النوعArticle
الصفحات1-15
رقم العدد1
رقم المجلد10
dc.accessType Open Access


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