New anti-corrosion inhibitor (3ar,6ar)-3a,6a-di-p-tolyltetrahydroimidazo[4,5-d]imidazole-2,5(1 h,3h)-dithione for carbon steel in 1 M HCl medium: gravimetric, electrochemical, surface and quantum chemical analyses
![Thumbnail](/bitstream/handle/10576/34688/New%20anti-corrosion%20inhibitor%20%283ar%2c6ar%29-3a%2c6a-di-p-tolyltetrahydroimidazo%5b4%2c5-d%5dimidazole-2%2c5%281%20h%2c3h%29-dithione%20for%20carbon%20steel%20in%201%20M%20HCl%20medium%20gravimetric%2c%20electrochemical%2c%20surface%20and%20quantum%20chemical%20analyses.pdf.jpg?sequence=4&isAllowed=y)
View/ Open
Publisher version (Check access options)
Check access options
Date
2020-10-01Author
Berdimurodov, ElyorKholikov, Abduvali
Akbarov, Khamdam
Xu, Guobao
Abdullah, Aboubakr M.
Hosseini, Morteza
...show more authors ...show less authors
Metadata
Show full item recordAbstract
The inhibition of (3ar,6ar)-3a,6a-di-p-tolyltetrahydroimidazo[4,5-d]imidazole-2,5(1 h,3h)-dithione (TTHIIDT) for carbon steel was full characterized in a 1 M hydrochloride acid environment at various inhibitor concentrations and temperatures by the gravimetric, electrochemical, surface and quantum chemical analyses. The obtained results confirmed that the inhibition efficiency of TTHIIDT was over 95–97% and nearly stable in the rise of temperature and concentration; TTHIIDT was mixed type inhibitor and effectively influenced both anodic and cathodic corrosion reactions; a protective hydrophobic thin layer of this inhibitor on the carbon steel surface is more stable and non soluble in 1 M HCl medium; this inhibitor adsorbed endothermically on the carbon steel surface by the chemical and physical adsorption processes. The quantum chemical calculations supported the experimental results and showed that the inhibition efficiency is depends on the structure of inhibitor.
Collections
- Center for Advanced Materials Research [1349 items ]