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AuthorSidiq, N.
AuthorBhat, M.A.
AuthorKhan, K.Z.
AuthorKhuroo, M.A.
Available date2016-02-08T14:21:27Z
Publication Date2014-10
Publication NameTransition Metal Chemistry
ResourceScopus
CitationSidiq, N., Bhat, M.A., Khan, K.Z., Khuroo, M.A. "Kinetic investigations into the synthesis of disulphides via tetrathiomolybdate as a sulphur-transfer reagent." (2014) Transition Metal Chemistry, 39 (7), pp. 781-787.
ISSN0340-4285
URIhttp://dx.doi.org/10.1007/s11243-014-9860-7
URIhttp://hdl.handle.net/10576/4132
AbstractKinetic and mechanistic aspects of the conversion of halides to disulphides using benzyl triethyl ammonium tetrathiomolybdate as sulphur-transfer reagent were investigated. The reaction follows a 1:1 stoichiometry with overall second-order kinetics and involves the formation of monosulphides in addition to disulphides. In the light of our observations, we propose a nucleophilic substitution: carbon-metal-carbon (S<inf>N</inf>-CMC) reaction mechanism. The proposed mechanism, besides accounting for all of our experimental observations, also explains many aspects of such reactions that have been reported earlier by various groups.
Languageen
PublisherKluwer Academic Publishers
SubjectCatalysis
Physical chemistry
Inorganic chemistry
Mole fraction ratio
TitleKinetic investigations into the synthesis of disulphides via tetrathiomolybdate as a sulphur-transfer reagent
TypeArticle
Pagination781-787
Issue Number7
Volume Number39
dc.accessType Abstract Only


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