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المؤلفM., Imran
المؤلفYousaf, Ammar Bin
المؤلفKasak, Peter
المؤلفZeb, Akif
المؤلفZaidi, Syed Javaid
تاريخ الإتاحة2023-04-05T08:58:26Z
تاريخ النشر2017-09-30
اسم المنشورJournal of Catalysis
المعرّفhttp://dx.doi.org/10.1016/j.jcat.2017.06.019
الاقتباسImran, M., Yousaf, A. B., Kasak, P., Zeb, A., & Zaidi, S. J. (2017). Highly efficient sustainable photocatalytic Z-scheme hydrogen production from an α-Fe2O3 engineered ZnCdS heterostructure. Journal of Catalysis, 353, 81-88.
الرقم المعياري الدولي للكتاب0021-9517
معرّف المصادر الموحدhttps://www.sciencedirect.com/science/article/pii/S0021951717302269
معرّف المصادر الموحدhttp://hdl.handle.net/10576/41695
الملخصWe present an α-Fe2O3/Zn0.4Cd0.6S heterostructure that shows visible light photocatalytic H2 production as high as 536.8μmolh−1 with apparent quantum efficiency of 11.2% at 420nm. The UV–vis diffuse reflectance spectra of as-synthesized α-Fe2O3/Zn0.4Cd0.6S heterostructure reveal efficient absorption in the visible region, which is a key factor in the enhanced catalytic activity. Moreover, the increase in charge separation efficiency of α-Fe2O3/Zn0.4Cd0.6S suggested by electrochemical impedance spectroscopy and photocurrent response also results in enhanced photocatalytic H2 production. The interface contact between α-Fe2O3 and Zn0.4Cd0.6S ascertained from HRTEM images promotes the recombination of photogenerated electrons from the conduction band of α-Fe2O3 and holes from the valence band of Zn0.4Cd0.6S, thus enhancing the utilization of solar light and increasing the efficiency. Our coupling approach to synthesizing an efficient Z-scheme photocatalyst provides insight into the design of further solar energy utilization photocatalysts.
راعي المشروع- USTC/Anhui Government Scholarships programme - CAS-TWAS President's Fellowship programme. - Qatar National Research Fund (a member of the Qatar Foundation) - grant # NPRP [9—219-2-105].
اللغةen
الناشرElsevier
الموضوعZ-scheme water splitting
Photocatalysis
Hydrogen production
α-Fe2O3
Zn0.4Cd0.6S
العنوانHighly efficient sustainable photocatalytic Z-scheme hydrogen production from an α-Fe2O3 engineered ZnCdS heterostructure
النوعArticle
الصفحات81-88
رقم المجلد353
ESSN1090-2694
dc.accessType Open Access


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