Aluminium doped ZnO nanostructures for efficient photodegradation of indigo carmine and azo carmine G in solar irradiation

Abstract

Aluminium doped zinc oxide (AZO) nanomaterials (AlxZn1-xO) with x fraction varying as 0.02 and 0.04 were synthesized using the auto-combustion method using glycine as a fuel. The synthesized catalysts were characterized with X-ray diffraction (XRD), UV–Visible Spectroscopy (UV–Vis), Raman spectroscopy, Photoluminescence (PL) spectroscopy, and High Resolution Transmission Electron Microscopy (HR-TEM). XRD results showed that synthesized materials possessed good crystallinity, while UV–VIS was employed to find the band gaps of synthesized materials. Raman was used to determine the vibrational modes in the synthesized nanoparticles, while TEM analysis was performed to study the morphology of the samples. Industrial effluents such as indigo carmine and azo carmine G were used to test the photodegradation ability of synthesised catalysts. Parameters such as the effect of catalyst loading, dye concentration and pH were studied. The reduction in crystallite size, band gap and increased lattice strain for the 4% AZO was the primary reason for the degradation in visible irradiation, degrading 97 and 99% equimolar concentrations of indigo carmine and azo carmine G in 140 min. The Al doped ZnO was found to be effective in faster degradation of dyes as compared to pure ZnO in presence of natural sunlight.