Proton And Carbon-13 Nuclear Magnetic Resonance Of Some 4-Amino-3-Alkyl (Aryl)-5-Thio-1,2,4-Triazolines And Their Derivatives
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The proton and carbon-13 NMR spectra of some 4-amino-3-alkyl(aryl)-5-thio-1,2,4-triazolines, some 3-alkyl-5-thio- 1,2,4-triazolines and some 4-amino-3-aryl-5-thio-l,2,4-triazoles were measured in DMSO-d6 as solvent. The chemical shift for each proton and carbon in these compounds were assigned. The 'H, chemical shift of N-H protons of the thioamide group and the "C chemical shift of C(3) in the triazolines were found to be sensitive to the substituent R (alkyi or aryl) at C(3), and correlated to Taft substituent constant CT*. The deprotonation constants p^ of the 4-amino-l,2,4-triazolines were correlated linearly with the proton chemical shift, 8, of the thioamide N-H protons.