Synthesis And Spectroscopic Studies On Some Ruthenium(II) Complexes

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Author Baghilaf, A. O. [احمد عمر بغلف] en_US
Author Banaser, K. en_US
Author Hashem, H. Y. en_US
Author Bishry, A. Ali en_US
Author Ishaq, M. en_US
Available date 2009-11-25T15:19:48Z en_US
Publication Date 1994 en_US
Citation Qatar University Science Journal, 1994, Vol. 14, No. خاص, Pages 75-79. en_US
URI http://hdl.handle.net/10576/9874 en_US
Abstract The salt [RuCl2(CO)2ln has proved very useful precursor for the syntheses of a variety of organometallic complexes of transition metals. The compounds of dichlorodicarbonylruthenium(II) of the formula [RuCl2(CO)22L] or [RuCl2(CO)2L'J where L= monodentate ligands such as tetramethylthiourea or substituted ureas, naphthisoxazole, 2-aminobenzthiazole or thioacetamide and L' = bidentate ligands such as 1,2-diaminoethane, 2,2'-dipyridylamine, 1-acetylferrocenethiosemicarbazone (1-AFTSC) or 1-acetylferrocenesemicarbazone (1-AFSC) have been prepared. The versatile nature of these ligands (L or L) has shown that they react readily with [RuCl2(CO)2ln giving very stable Ru(II) complexes. For example, the complex 1-acetylferrocenethiosemicarbazone, 7i-C5H5FeC5H4.CH3C=N.NH.CS.NH2. (1-AFTSC) or 1-acetylferrocenesemicarbazone, 7i-C5H5FeC5H4CH3C=N. NH.CO.NH2- (1-AFSC) acts as bidentate ligand in which thiosemicarbazone or semicarbazone moiety acts as bridge between two metal systems giving bimetallic complexes. Thus, the reaction of [RuCl2(CO)2]n with 1-AFTSC or 1-AFSC yields 1-acetylferrocenethiosemicarbazone dichlorodicarbonylruthenium (II) [7C-C5H5FeC5H4CH3C=N. NH.CS.NH2RuCl2(CO)2] or 1-acetylferrocenesemicarbazone dichlorodicarbonylruthenium(H) [7C-C5H5FeC5H4CH3C=N.NH.CO.NH2.RuCl2(CO)2] complexes respectively as shown in the scheme of reactions (Fig. 1). Similarly reactions of CuX2(X = Cl or Br) and NiCl2.XH2O with 1-AFTSC yield respective organometallic complexes. All the complexes were identified by elemental analysis and were characterized by IR treated with [RuCl2(CO)2]n[8]. However, 1-acetylferrocenethiosemicarbazone, (7C-C5H5FeC5H4CH3 C=N.NH.CS.NH2) has proved very useful bidentate ligand. and ^H-NMR spectroscopy and elemental analyses. en_US
Abstract إستخدم متراكب ثنافي الكلوريد ثلْافي الكربونيل للروثنيوم الثنائي كمادة أولية لتحضير متراكبات الروثنيوم الثنائي مع مرتبطات إِحادية المخلب المتعادلة وكدْلك مع المرتبطات ثنائية المخلب مثل اثيلين ثنافي الأمين ومشتقات الفروسين ثيوسيمكربازوق ه ولقد تم التعرف على تلك المتراكبات باستخدام طيف الأشعة تحت الحمراء والرنين النووي المغناطيسي للبروتون وكذلك التحليل العنصسي . ar
Language en en_US
Publisher Qatar University en_US
Subject Inroganic Chemistry en_US
Subject الكيمياء غير العضوية ar
Subject Ferrocene thiosemicarbazone en_US
Title Synthesis And Spectroscopic Studies On Some Ruthenium(II) Complexes en_US
Alternative Title تحضير ودراسات طيفية على بعض متراكبات الروثنيوم الثنائي ar
Type Article en_US
Pagination 75-79 en_US
Issue Number خاص en_US
Volume Number 14 en_US


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