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Synthesis of Novel Aqua ƞ4-NNNO/Cu(II) Complexes as Rapid and Selective Oxidative Catalysts for O-Catechol: Fluorescence, Spectral, Chromotropism and Thermal Analyses
(
MDPI
, 2021 , Article)
A new tetradentate Schiff base (SB), (E)-4-fluoro-2-(1-((2-(piperazin-1-yl)ethyl)imino)ethyl)phe-nol, was synthesized from condensation of 2-(1-piperazinyl)ethylamine and 5-fluoro-2-hydroxyacetophe-none. This ligand was ...
Concentrations of essential and toxic elements and health risk assessment in brown rice from Qatari market
(
Elsevier
, 2022 , Article)
Twenty-two brown rice varieties available in the Qatari market were analyzed for essential and toxic elements by ICP-MS. Found concentrations (µg/kg) were: As: 171 ± 78 (62–343), Cd: 42 ± 60 (4–253), Cr: 515 ± 69 (401–639), ...
Synthesis of thioether-functional poly(olefin)s via ruthenium-alkylidene initiated ring-opening metathesis polymerization
(
John Wiley and Sons Inc.
, 2019 , Article)
Ring-opening metathesis polymerization (ROMP) of thioether-derived oxanorbornene imide (M1) and its copolymerization with various cycloolefin comonomers such as cyclopentene (M2), cyclopent-3-en-1-ol (M3), cycloheptene ...
Engineering of nickel based catalyst for direct urea fuel cell-energy from municipal liquid waste (Mlw)
(
Nova Science Publishers, Inc.
, 2019 , Book chapter)
Alternatives to conventional fuels are required to meet the global energy demand, urea is a relatively non-toxic crystalline substance that is perhaps best known for its presence in municipal liquid waste (MLW) and ...
Spectrophotometric Determination of the Honey Bee Quality
(
Qatar University Press
, 2021 , Poster)
Honey produced by bees from nectar in flowers and plants, is an aqueous supersaturated sugar solution, mainly monosaccharide (fructose and glucose) (70%–80%) and water (10%–20%). 5-Hydroxymethylfurfural (5-HMF) content in ...
One minute microwave synthesis of [O2N-Ph-CH2-Py = N(Me)2]+[Cl]− ionic liquid: XRD/HSA-interactions, physicochemical, optical, thermal and A DFT/TD-DFT analysis
(
Elsevier
, 2021 , Article)
1-(4-nitrobenzyl)-4-dimethylaminopyridinium chloride, [O2N-Ph-CH2-Py = N(Me)2]+[Cl]−, was made available in good yield and within one minute using microwave assisted reaction (MW). The ionic liquid product resonance structure ...
Investigation on the effect of LiTFSI salt on PVDF-based Solid Polymer Electrolyte Membranes for Lithium-Ion Batteries
(
Qatar University Press
, 2021 , Poster)
Solid polymer electrolytes provide an alternative approach to providing improved safety whilst concurrently acting as a performance enhanced separator within Lithium-ion batteries (LIBs). This investigation studies the ...
Detecting Organic Nitrogen with 1H-15N HMBC Spectra
(
Qatar University Press
, 2021 , Poster)
NMR spectroscopy has been the most important tool for organic chemistry research, providing detailed structure information. While 1H and 13C NMR spectra were frequently measured, 15N NMR spectra were relatively rare, even ...
The Carcinogenic and Non-Carcinogenic Health Risks of Metal(oid)s Bioaccumulation in Leafy Vegetables: A Consumption Advisory
(
Frontiers Media
, 2021 , Article)
High levels of metal(oid)s in soil or food pose a severe health risk to humans. The potential toxicants find their way into the living systems via the food chain, following bioaccumulation in edible plants, including leafy ...
Systematic laboratory approach to produce Mg-rich carbonates at low temperature
(
Royal Society of Chemistry
, 2021 , Article)
Dolomite is a common Mg-rich carbonate in the geological record, but the mechanism of its formation remains unclear. At low temperature, the incorporation of magnesium ions into the carbonate minerals necessary to form ...