Spectrophotometric and thermal studies on the charge – Transfer complexes of 4-(aminomethyl) piperidine as donor with σ- and π-electron acceptors
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The spectroscopic characteristics of the solid charge-transfer molecular complexes (CT) formed in the reaction of the electron donor 4-(aminomethyl) piperidine (4AMP) with the σ-acceptor iodine and the π-acceptors 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TBCHD) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been studied in chloroform at 25°C. These were investigated through electronic, infrared spectra and thermal analysis as well as elemental analysis.The results show that the formed solid CT-complexes have the formulas [(4AMP)I]+I3-, [(4AMP)(DDQ)2] and [(4AMP)(TBCHD)] while in the case of 4AMP-TCNQ reaction, a short-lived CT complex is formed followed by rapid N-substitution by TCNQ forming the final reaction product 7,7,8-tricyano-8-aminomethylpiperidinylquinodimethane [TCAMPQDM] in full agreement with the known reaction stoichiometries in solution as well as the elemental measurements and the thermal analysis confirmed the structure of the obtained compounds. The formation constant kCT, molar extinction coefficient εCT, free energy change ΔG0 and CT energy ECT have been calculated for the CT-complexes [(4AMP)I]+I3-, [(4AMP)(DDQ)2] and [(4AMP)(TBCHD)].
http://hdl.handle.net/10576/5264 ; http://dx.doi.org/10.1016/j.saa.2013.09.091
- Chemistry & Earth Sciences [95 items ]