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AuthorPham M.
AuthorHarris J.
AuthorShaffer J.
AuthorDaniel A.
AuthorChowdhury S.
AuthorAli A.
AuthorBanerjee S.
AuthorAhmed S.
Available date2020-03-18T10:47:17Z
Publication Date2019
Publication NameJournal of Materials Science: Materials in Electronics
ResourceScopus
ISSN9574522
URIhttp://dx.doi.org/10.1007/s10854-019-01275-3
URIhttp://hdl.handle.net/10576/13435
AbstractWe have simulated the operation and functionality of a working Bi-based perovskite solar cell device using GPVDM and compared it against a Pb-based device. The results are extremely promising in that they showcase comparable cell efficiencies, with the Bi-based device showing a highest 20.0% efficiency (Jsc of 256 A.m-2, Voc of 1.04 V, FF of 0.75) at 450 nm active layer thickness compared to 23.4% of its Pb counterpart (Jsc of 349.3 A.m-2, Voc of 0.81 V, FF of 0.83) at 850 nm active layer thickness. The Bi-based device can thus be manufactured at approximately half its Pb-counterpart active layer thickness, to give its optimal efficiency value. A deeper study of each of the Jsc, Voc and FF trends provide keen insight into charge transfer kinetics within the device, paving the way to optimal experimental setups for fabricating the most efficient non-toxic perovskite devices.
SponsorThis work was supported by the New York Clean Energy Grant from SUNY Buffalo State.
Languageen
PublisherSpringer New York LLC
TitleBismuth perovskite as a viable alternative to Pb perovskite solar cells: device simulations to delineate critical efficiency dynamics
TypeArticle
Pagination9438-9443
Issue Number10
Volume Number30


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