CO 2 adsorption studies on Prussian blue analogues
| Author | Karadas, F. |
| Author | El-Faki, H. |
| Author | Deniz, E. |
| Author | Yavuz, C.T. |
| Author | Aparicio, S. |
| Author | Atilhan, M. |
| Available date | 2023-02-22T10:05:14Z |
| Publication Date | 2012 |
| Publication Name | Microporous and Mesoporous Materials |
| Resource | Scopus |
| Abstract | Carbon dioxide (CO2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm® sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN)6]3− (Mdouble bondCo, Fe) solution with solutions of M2+ (Mdouble bondMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption. |
| Sponsor | This paper was made possible by the support of an NPRP grant (No. NPRP-08-670-1-124) from The Qatar National Research Fund . The statements made herein are solely the responsibility of the authors. |
| Language | en |
| Publisher | Elsevier Inc. |
| Subject | Adsorption Carbon dioxide High pressure Monte Carlo Prussian blue analogues |
| Type | Article |
| Pagination | 91-97 |
| Volume Number | 162 |
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Chemical Engineering [1129 items ]