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CO 2 adsorption studies on Prussian blue analogues

المؤلفKaradas, F.
المؤلفEl-Faki, H.
المؤلفDeniz, E.
المؤلفYavuz, C.T.
المؤلفAparicio, S.
المؤلفAtilhan, M.
تاريخ الإتاحة2023-02-22T10:05:14Z
تاريخ النشر2012
اسم المنشورMicroporous and Mesoporous Materials
المصدرScopus
معرّف المصادر الموحدhttp://dx.doi.org/10.1016/j.micromeso.2012.06.019
معرّف المصادر الموحدhttp://hdl.handle.net/10576/40287
الملخصCarbon dioxide (CO2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm® sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN)6]3− (Mdouble bondCo, Fe) solution with solutions of M2+ (Mdouble bondMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption.
راعي المشروعThis paper was made possible by the support of an NPRP grant (No. NPRP-08-670-1-124) from The Qatar National Research Fund . The statements made herein are solely the responsibility of the authors.
اللغةen
الناشرElsevier Inc.
الموضوعAdsorption
Carbon dioxide
High pressure
Monte Carlo
Prussian blue analogues
العنوانCO 2 adsorption studies on Prussian blue analogues
النوعArticle
الصفحات91-97
رقم المجلد162


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