New electrospun polystyrene/Al2O3 nanocomposite superhydrophobic coatings; Synthesis, characterization, and application
المؤلف | Radwan A.B. |
المؤلف | Abdullah A.M. |
المؤلف | Mohamed A.M.A. |
المؤلف | Al-Maadeed M.A. |
تاريخ الإتاحة | 2020-02-05T08:53:07Z |
تاريخ النشر | 2018 |
اسم المنشور | Coatings |
المصدر | Scopus |
الرقم المعياري الدولي للكتاب | 20796412 |
الملخص | The effect of electrospinning operational parameters on the morphology, surface roughness, and wettability of different compositions of electrospun polystyrene (PS)-aluminum oxide (Al2O3) nanocomposite coatings was investigated using different techniques. For example, a scanning electron microscope (SEM) coupled with an energy dispersive X-ray (EDX) unit, a Fourier transform infrared (FTIR) spectrometer, an atomic force microscope (AFM), and water contact angle (WCA), and contact angle hysteresis (CAH) measurements using the sessile droplet method, were used. The latter used 4 μL of distilled water at room temperature. PS/Al2O3 nanocomposite coatings exhibited different morphologies, such as beaded fibers and microfibers, depending on the concentration ratio between the PS and Al2O3 nanoparticles and the operational parameters of the electrospinning process. The optimum conditions to produce a nanocomposite coating with the highest roughness and superhydrophobic properties (155° ± 1.9° for WCA and 3° ± 4.2° for CAH) are 2.5 and 0.25 wt % of PS and Al2O3, respectively, 25 kV for the applied potential and 1.5 mL·h-1 for the solution flow rate at 35 °C. The corrosion resistance of the as-prepared coatings was investigated using the electrochemical impedance spectroscopy (EIS) technique. The results have revealed that the highly porous superhydrophobic nanocomposite coatings (SHCs) possess a superior corrosion resistance that is higher than the uncoated Al alloy by three orders of magnitude. © 2018 by the authors. |
راعي المشروع | Acknowledgments: This publication was supported by Qatar University Internal Grant No. GCC-2017-012. The findings achieved herein are solely the responsibility of the authors. Thanks are also due to Anton Popelka for assistance with the AFM analysis. |
اللغة | en |
الناشر | MDPI AG |
الموضوع | Aluminum oxide Coating Electrospinning Morphology Nanocomposite Polystyrene Superhydrophobic Surface roughness |
النوع | Article |
الصفحات | - |
رقم العدد | 2 |
رقم المجلد | 8 |
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