• English
    • العربية
  • العربية
  • Login
  • QU
  • QU Library
  •  Home
  • Communities & Collections
  • Help
    • Item Submission
    • Publisher policies
    • User guides
    • FAQs
  • About QSpace
    • Vision & Mission
View Item 
  •   Qatar University Digital Hub
  • Qatar University Institutional Repository
  • Academic
  • Research Units
  • Center for Advanced Materials
  • Center for Advanced Materials Research
  • View Item
  • Qatar University Digital Hub
  • Qatar University Institutional Repository
  • Academic
  • Research Units
  • Center for Advanced Materials
  • Center for Advanced Materials Research
  • View Item
  •      
  •  
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Improved electrochemical performance of SiO2-coated Li-rich layered oxides-Li1.2Ni0.13Mn0.54Co0.13O2

    Thumbnail
    View/Open
    s10854-020-04481-6.pdf (3.433Mb)
    Date
    2020
    Author
    James Abraham, Jeffin
    Nisar, Umair
    Monawwar, Haya
    Abdul Quddus, Aisha
    Shakoor, R. A.
    Saleh, Mohamed I.
    Kahraman, Ramazan
    Al-Qaradawi, Siham
    Aljaber, Amina S.
    ...show more authors ...show less authors
    Metadata
    Show full item record
    Abstract
    Lithium-rich layered oxides (LLOs) such as Li1.2Ni0.13Mn0.54Co0.13O2 are suitable cathode materials for future lithium-ion batteries (LIBs). Despite some salient advantages, like low cost, ease of fabrication, high capacity, and higher operating voltage, these materials suffer from low cyclic stability and poor capacity retention. Several different techniques have been proposed to address the limitations associated with LLOs. Herein, we report the surface modification of Li1.2Ni0.13Mn0.54Co0.13O2 by utilizing cheap and readily available silica (SiO2) to improve its electrochemical performance. Towards this direction, Li1.2Ni0.13Mn0.54Co0.13O2 was synthesized utilizing a sol-gel process and coated with SiO2 (SiO2 = 1.0 wt%, 1.5 wt%, and 2.0 wt%) employing dry ball milling technique. XRD, SEM, TEM, elemental mapping and XPS characterization techniques confirm the formation of phase pure materials and presence of SiO2 coating layer on the surface of Li1.2Ni0.13Mn0.54Co0.13O2 particles. The electrochemical measurements indicate that the SiO2-coated Li1.2Ni0.13Mn0.54Co0.13O2 materials show improved electrochemical performance in terms of capacity retention and cyclability when compared to the uncoated material. This improvement in electrochemical performance can be related to the prevention of electrolyte decomposition when in direct contact with the surface of charged Li1.2Ni0.13Mn0.54Co0.13O2 cathode material. The SiO2 coating thus prevents the unwanted side reactions between cathode material and the electrolyte. 1.0 wt% SiO2-coated Li1.2Ni0.13Mn0.54Co0.13O2shows the best electrochemical performance in terms of rate capability and capacity retention.
    DOI/handle
    http://dx.doi.org/10.1007/s10854-020-04481-6
    http://hdl.handle.net/10576/34832
    Collections
    • Center for Advanced Materials Research [‎1482‎ items ]
    • Chemical Engineering [‎1195‎ items ]
    • Chemistry & Earth Sciences [‎605‎ items ]
    • Electrical Engineering [‎2821‎ items ]

    entitlement


    Qatar University Digital Hub is a digital collection operated and maintained by the Qatar University Library and supported by the ITS department

    Contact Us | Send Feedback
    Contact Us | Send Feedback | QU

     

     

    Home

    Submit your QU affiliated work

    Browse

    All of Digital Hub
      Communities & Collections Publication Date Author Title Subject Type Language Publisher
    This Collection
      Publication Date Author Title Subject Type Language Publisher

    My Account

    Login

    Statistics

    View Usage Statistics

    About QSpace

    Vision & Mission

    Help

    Item Submission Publisher policiesUser guides FAQs

    Qatar University Digital Hub is a digital collection operated and maintained by the Qatar University Library and supported by the ITS department

    Contact Us | Send Feedback
    Contact Us | Send Feedback | QU

     

     

    Video